The bond order depends on the number of electrons in the bonding and antibonding orbitals.

Which of the following statements are correct about bond order?

1.  Bond order can have a negative value.

2.  It always has an integral value.

3.  It is always  a non zero quantity

4.  It can assume any value-positive or fractional, including zero.

What is the best description of the geometry of the nitrogen atoms in dimethylnitrosamine, ${\left({\mathrm{CH}}_3\right)}_2\mathrm{NNO}$?

         N bounded to $C{H}_3$ groups                       N bonded to O

1.  Trigonal planar                                         Linear

2.  Trigonal planar                                         Bent

3.  Trigonal pyramidal                                   Linear

4.  Trigonal pyramidal                                   Bent

The following diagram is sometimes used to illustrates the structure of benzene $C_6{H}_6$

Which of the statements concerning the structure of benzene is false?

1.  The double bonds oscillate rapidly back and forth between adjacent pairs of carbon atoms

2.  The $\mathrm{H} -\mathrm{C} -\mathrm{C} \mathrm{angles} \mathrm{are} 120°$

3.  The carbon atoms form a flat hexagonal ring

4.  Above structures are resonance structures

The diamagnetic species among the following is:

1. NO

2. ${\mathrm{NO}}_2$

3. ${\mathrm{O}}_2$

4. ${\mathrm{CO}}_2$

Removing an electron from molecular oxygen, $O_2$, to form the dioxygenyl cation, ${O^{+}}_2$, causes what changes in the bond length and in the number of unpaired electrons?

          Bond length                            Number of unpaired electrons

1.  Increase                                       Increase

2.  Increase                                       Decrease

3.  Decrease                                      Increase

4.  Decrease                                      Decrease

How many carbon-carbon double bonds are present in linolenic acid, $\mathrm{\alpha }-{\mathrm{C}}_{17}{\mathrm{H}}_{29}\mathrm{COOH}$?

1.  1

2.  2

3.  3

4.  4

The formulae and boiling points of three compounds are given in this table.

The trend in boiling points is best attributed to variations in

1.  Covalent bonding

2.  Dipole forces

3.  Dispersion forces

4.  Hydrogen bonding

Three monosulfur fluorides are known : ${\mathrm{SF}}_2,<mspace\; width="1em"></mspace>{\mathrm{SF}}_4<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{SF}}_6$. Of these, polar species include

1.  $S{F}_2$ Only

2.  $S{F}_4$ Only

3.  $S{F}_2$ and $S{F}_4$ Only

4.  $S{F}_2$, $S{F}_4$ and $S{F}_6$

Which ionic compound has the largest lattice energy?

1.  LiF

2.  BeO

3.  KBr

4.  CaS

The boiling points of ${\mathrm{CH}}_3{\mathrm{COCH}}_3,<mspace\; width="1em"></mspace>{\mathrm{CH}}_3{\mathrm{COC}}_2{\mathrm{H}}_5<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{CH}}_3{\mathrm{COC}}_3{\mathrm{H}}_7$ are $56°\mathrm{C},<mspace\; width="1em"></mspace>80°\mathrm{C},<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>102°\mathrm{C}$, respectively. This increase is best attributed to an increase in which of the following?

l.  Dipole-dipole interactions.

ll.  Dispersion forces.

lll.  Hydrogen bonding.

1.  l only

2.   I and ll 

3.  lll only

4.  ll and lll only