Which one of the following is most reactive towards electrophilic attack?

1.		2.
3.		4.

The volume occupied by one water molecule (density = 1 g cm^-3) is:

1. $9.0\times {10}^{-23}$ $$ ${\mathrm{cm}}^3$

2. $6.023\times {10}^{-23}$ $$ ${\mathrm{cm}}^3$

3. $3.0\times {10}^{-23}$ $$ ${\mathrm{cm}}^3$

4. $5.5\times {10}^{-23}$ $$ ${\mathrm{cm}}^3$

Which of the following complexes has the highest paramagnetic behaviour?

(where gly = glycine, en = ethylenediamine, ox = oxalate ion and bpy = bipyridyl moieties )
(At no : Ti= 22, V = 23, Fe = 26, Co = 27)

1. [V(gly)₂(OH)₂(NH₃)₂]⁺

2. [Fe(en)(bpy)(NH₃)₂]²⁺

3.  [Co(ox)₂(OH)₂]^-

4. [Ti(NH₃)₆]³⁺

If a gas expands at a constant temperature, it indicates that:

1. Kinetic energy of the molecules decreases

2. The pressure of the gas increases

3. The kinetic energy of the molecules remains the same

4. The number of molecules of gas increases

In a S_N2 substitution reaction of the type 
\(\mathrm{R}-\mathrm{Br}+\mathrm{Cl}^{-} \xrightarrow{\mathrm{DMF}} \mathrm{R}-\mathrm{Cl}+\mathrm{Br}^{-}\)

one of the following that has the highest relative rate is:
 

1.	\(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{Br}\)	2.
3.		4.	\(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Br}\)

Number of moles of \(MnO^-_4\) required to oxidise one mole of ferrous oxalate completely in an acidic medium will be:

If the concentration of OH ' ions in the reaction