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| List-I (Mixture) |
List-II (Method of Separation) |
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| A. | \( \mathrm{CHCl}_3+ \mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2 \) | I. | Distillation under reduced pressure |
| B. | Crude oil in petroleum industry | II. | Steam distillation |
| C. | Glycerol from spent-lye | III. | Fractional distillation |
| D. | Aniline-water | Iv. | Simple distillation |
| A | \([\mathrm{Ne}] 3 \mathrm{~s}^1\) | B | \([\mathrm{Ar}] 3d^3 \mathrm{~4s}^2\) |
| C | \([\mathrm{Kr}] 4 \mathrm{~d}^{10} 5 \mathrm{~s}^2 5 \mathrm{p}^5\) | D | \([\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^1\) |
| E | \(\mathrm{[R n] }5 f^0 6 d^2 7 s^2\) | ||
| 1. | D and E only | 2. | A, C and D only |
| 3. | B and E only | 4. | A and C only |
| A. | \(\log \mathrm{K}=\log \mathrm{K}_{\mathrm{a}_1}+\log \mathrm{K}_{\mathrm{a}_2}+\log \mathrm{K}_{\mathrm{a}_3}\) |
| B. | \(\mathrm{H}_3 \mathrm{PO}_4\) is a stronger acid than \(\mathrm{H}_2 \mathrm{PO}_4^{-}\) and \(\mathrm{HPO}_4^{2-} .\) |
| C. | \(\mathrm{K}_{a_1} >\mathrm{~K}_{\mathrm{a}_2}>\mathrm{K}_{\mathrm{a}_3} \) |
| D. | \(\mathrm{K}_{\mathrm{a}_1}=\frac{\mathrm{K}_{\mathrm{a}_3}+\mathrm{K}_{\mathrm{a}_2}}{2}\) |
| List-I (Ion) |
List-II (Group Number in Cation Analysis) |
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| A. | \(Co^{2+}\) | I. | Group-I |
| B. | \(Mg^{2+}\) | II. | Group-III |
| C. | \(Pb^{2+}\) | III. | Group-IV |
| D. | \(Al^{3+}\) | IV. | Group-VI |
| 1. | A-III, B-II, C-IV, D-I | 2. | A-III, B-II, C-I, D-IV |
| 3. | A-III, B-IV, C-II, D-I | 4. | A-III, B-IV, C-I, D-II |
| Statement I: | Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at \(273-278~ \text{K}.\) It decomposes easily in the dry state. |
| Statement II: | Insertion of iodine into the benzene ring is difficult, and hence iodobenzene is prepared through the reaction of benzenediazonium salt with \(KI.\) |
| 1. | Statement I is correct; Statement II is incorrect |
| 2. | Statement I is incorrect; Statement II is correct |
| 3. | Both Statement I and Statement II are correct |
| 4. | Both Statement I and Statement II are incorrect |
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