The potential energy (y) curve for H2 formation as a function of internuclear distance (x) of the H atoms is shown below.
The bond energy of H2 is:
| 1. | (b – a) | 2. | \(\dfrac{\left(\right. c - a \left.\right)}{2}\) |
| 3. | \(\dfrac{\left(\right. b - a \left.\right)}{2}\) | 4. | (c – a) |
The incorrect oxidation number of the underlined atom in the following species is:
| 1. | Cu2O is -1 | 2. | Cl\(O_{3}^{-}\) is +5 |
| 3. | K2Cr2O7 is +6 | 4. | HAuCl4 is +3 |
1. Fe₃[Fe(CN)₆]₂
2. Fe₄[Fe(CN)₆]₃
3. Fe₄[Fe(CN)₆]₂
4. Fe₃[Fe(CN)₆]₃
Match the compounds of Xe in Column I with the molecular structure in Column II.
| Column-I | Column-II | ||
| (a) | XeF2 | (i) | Square planar |
| (b) | XeF4 | (ii) | Linear |
| (c) | XeO3 | (iii) | Square pyramidal |
| (d) | XeOF4 | (iv) | Pyramidal |
| (a) | (b) | (c) | (d) | |
| 1. | (ii) | (i) | (iii) | (iv) |
| 2. | (ii) | (iv) | (iii) | (i) |
| 3. | (ii) | (iii) | (i) | (iv) |
| 4. | (ii) | (i) | (iv) | (iii) |
If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapor pressure to 80 %, the molar mass (in g mol–1) of the solute is:
[Molar mass of n-octane is 114 g mol–1]
| 1. | 40 | 2. | 60 |
| 3. | 80 | 4. | 20 |
| 1. | Both Sc3+ and Zn2+ ions are colourless and form white compounds |
| 2. | In the case of Sc, 3d orbitals are partially filled but in Zn, these are fully filled. |
| 3. | The last electron is assumed to be added to the 4s level in the case of Zn |
| 4. | Both Sc and Zn do not exhibit variable oxidation states. |
At standard conditions, if the change in the enthalpy for the following reaction is –109 kJ mol–1
H2(g)+Br2(g)2HBr(g) and the bond energy of H2 and Br2 is 435 kJ mol–1 and 192 kJ mol–1 respectively, what is the bond energy (in kJ mol–1) of HBr?
| 1. | 368 | 2. | 736 |
| 3. | 518 | 4. | 259 |
For the reaction:
\(\mathrm{X}_2 \mathrm{O}_4(l) \rightarrow 2 \mathrm{XO}_2(g)\)
with the given values \(\Delta U = 2.1 \, \text{kcal}\) and \(\Delta S = 20 \, \text{cal K}^{-1}\) at \(300 \, \text{K}\), what is the value of \(\Delta G\)?
1. +2.7 kcal
2. –2.7 kcal
3. +9.3 kcal
4. –9.3 kcal
Match the following aspects with the respective metal:
| Aspects | Metal | ||
| (a) | The metal that reveals the maximum number of oxidation states | (i) | Scandium |
| (b) | The metal, although placed in a 3d block, is not considered a transition element | (ii) | Copper |
| (c) | The metal that does not exhibit variable oxidation states | (iii) | Manganese |
| (d) | The metal, which is in +1 oxidation state in aqueous solution, undergoes disproportionation | (iv) | Zinc |
Select the correct option:
| Options: | (a) | (b) | (c) | (d) |
| 1. | (i) | (iv) | (ii) | (iii) |
| 2. | (iii) | (iv) | (i) | (ii) |
| 3. | (iii) | (i) | (iv) | (ii) |
| 4. | (ii) | (iv) | (i) | (iii) |
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