| 1. | It results due to change of temperature and pH. |
| 2. | It results in the loss of biological activity of proteins. |
| 3. | A protein is formed from amino acids linked by peptide bonds. |
| 4. | Uncoiling of the helical structure takes place. |
| 1. | 2. | ||
| 3. | 4. |
| Assertion (A): | Chlorine is an electron-withdrawing group, yet it exhibits ortho- and para-directing behavior in electrophilic aromatic substitution. |
| Reason (R): | Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| 1. | |
| 2. | |
| 3. | |
| 4. |
| 1. | 4f orbitals are penultimate |
| 2. | 4f orbitals have a greater shielding effect |
| 3. | 5f orbitals have a poor shielding effect |
| 4. | 5f orbitals have a greater shielding effect |
Match the reagents (List-I) with the products (List-II) obtained from phenol:
| List-I | List-II | ||
| (A) | (i) NaOH (ii) CO2 (iii) H+ |
(I) | Benzoquinone |
| (B) | (i) Aqueous NaOH + CHCl3 (ii) H+ |
(II) | Benzene |
| (C) | Zn dust, \(\Delta\) | (III) | Salicylaldehyde |
| (D) | Na2Cr2O7, H2SO4 | (IV) | Salicylic acid |
| (A) | (B) | (C) | (D) | |
| 1. | (III) | (IV) | (I) | (II) |
| 2. | (II) | (I) | (IV) | (III) |
| 3. | (IV) | (III) | (II) | (I) |
| 4. | (IV) | (II) | (I) | (III) |
| List-I (quantum number) |
List-II (Orbital) |
||
| (A) | n = 2, \(\ell\) = 1 | (I) | 2s |
| (B) | n = 3, \(\ell\) = 2 | (II) | 3s |
| (C) | n = 3, \(\ell\) = 0 | (III) | 2p |
| (D) | n = 2, \(\ell\) = 0 | (IV) | 3d |
| (A) | (B) | (C) | (D) | |
| 1. | (III) | (IV) | (I) | (II) |
| 2. | (IV) | (III) | (I) | (II) |
| 3. | (IV) | (III) | (II) | (I) |
| 4. | (III) | (IV) | (II) | (I) |
| 1. | 1 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |
| 2. | 10 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
| 3. | 1 × 10–2 mol L–1 s–1 and 10 × 10–2 mol L–1 |
| 4. | 10 × 10–2 mol L–1 s–1 and 30 × 10–2 mol L–1 |