| 1. | 9.50 g | 2. | 1.25 g |
| 3. | 1.32 g | 4. | 3.65 g |
| 1. | \(O^+_2\) ion is diamagnetic. |
| 2. | The bond orders of \(O_2^{+},O_2,O^-_2\) and \(O_2^{2-}\) are 2.5, 2, 1.5, and 1, respectively. |
| 3. | \(C_2\) molecule has four electrons in its two degenerate \(\pi \) molecular orbitals. |
| 4. | \(H^+_2 \) ion has one electron. |

| 1. | zero order (y=rate and x=concentration), first order (y=rate and x=t1/2) |
| 2. | zero order (y=concentration and x=time), first order (y=t1/2 and x = concentration) |
| 3. | zero order (y=concentration and x= time), first order (y=rate constant and x= concentration) |
| 4. | zero order (y=rate and x=concentration), first order (y=t1/2 and x = concentration) |
| 1. | A racemic mixture shows zero optical rotation |
| 2. | SN1 reaction yields a 1:1 mixture of both enantiomers |
| 3. | The product obtained by SN2 reaction of haloalkane having chirality at the reactive site shows the inversion of configuration |
| 4. | Enantiomers are superimposable mirror images on each other |
| Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) |
| Statement II: | The boiling points of these hydrides increase with the increase in molar mass. |
Which of the following species will exhibit the maximum lone pair–lone pair electron repulsions?
1. \(\mathrm{XeF_2}\)For a first-order reaction A \(\rightarrow\) Products, initial concentration of A is 0.1 M, which becomes 0.001 M after 5 minutes. Rate constant for the reaction in min-1 is
| 1. | 0.2303 | 2. | 1.3818 |
| 3. | 0.9212 | 4. | 0.4606 |