| 1. | 1260 J | 2. | 2520 J |
| 3. | 5040 J | 4. | 0 J |
| 1. | sp2 and sp3 | 2. | sp2 and sp2 |
| 3. | sp3 and sp2 | 4. | sp3 and sp3 |
| 1. | 5375 × 10–3 g | 2. | 5.4 g |
| 3. | 5.38 g | 4. | 53.75 g |
Fluorine is known to be a stronger oxidizing agent than chlorine. Which of the following thermodynamic factors is the primary reason for this behavior?
| (a) |
The F–F bond has a low bond dissociation enthalpy. |
| (b) |
The fluoride ion (F⁻) has a high hydration enthalpy in aqueous solution. |
| (c) | The electron gain enthalpy of fluorine is less negative than that of chlorine. |
| (d) | Fluorine has a very small atomic size. |
| 1. | (a) and (b) only | 2. | (a) and (c) only |
| 3. | (a) and (d) only | 4. | (b) and (c) only |
| List-I (Complexes) | List-II (Type of isomer) | ||
| A. | [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 |
I. | Ionisation isomerism |
| B. | [Cr(NH3)6] [Co(CN)6] and [Cr(CN)6][Co(NH3)6] |
II. | Coordination isomerism |
| C. | [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 |
III. | Linkage isomerism |
| D. | [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2.H2O |
IV. | Solvate isomerism |
| (A) | (B) | (C) | (D) | |
| 1. | (III) | (I) | (II) | (IV) |
| 2. | (II) | (III) | (IV) | (I) |
| 3. | (III) | (II) | (I) | (IV) |
| 4. | (IV) | (III) | (II) | (I) |
| 1. | It results due to change of temperature and pH. |
| 2. | It results in the loss of biological activity of proteins. |
| 3. | A protein is formed from amino acids linked by peptide bonds. |
| 4. | Uncoiling of the helical structure takes place. |
| 1. | 2. | ||
| 3. | 4. |
| List-I (Defects) |
List-II (shown by) |
| (a) Frenkel defect | (i) non-ionic solids and density of the solid decreases. |
| (b) Schottky defect | (ii) non-ionic solids and density of the solid increases. |
| (c) Vacancy defect | (iii) ionic solids and density of the solid decreases. |
| (d) Interstitial defect |
(iv) ionic solids and the density of the solid remains constant. |
| (a) | (b) | (c) | (d) | |
| 1. | (i) | (ii) | (iii) | (iv) |
| 2. | (i) | (iii) | (ii) | (iv) |
| 3. | (iv) | (iii) | (ii) | (i) |
| 4. | (iv) | (iii) | (i) | (ii) |
| Assertion (A): | Chlorine is an electron-withdrawing group, yet it exhibits ortho- and para-directing behavior in electrophilic aromatic substitution. |
| Reason (R): | Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| 1. | |
| 2. | |
| 3. | |
| 4. |