| 1. | H3BO3 | 2. | B2O3 |
| 3. | Na2B2O5 | 4. | NaB3O5 |
| 1. | C < N < F < O | 2. | C < N < O < F |
| 3. | C < O < N < F | 4. | C < F < N < O |
| 1. | 3 | 2. | 2 |
| 3. | 4 | 4. | 1 |
| 1. | \(\text{C}_7\text{H}_5\text{Br}\) | 2. | \(\text{C}_6\text{H}_4\text{Br}_3\) |
| 3. | \(\text{C}_8\text{H}_9\text{Br}\) | 4. | \(\text{C}_{12}\text{H}_{22}\text{Br}\) |
| 1. | 1260 J | 2. | 2520 J |
| 3. | 5040 J | 4. | 0 J |
| 1. | sp2 and sp3 | 2. | sp2 and sp2 |
| 3. | sp3 and sp2 | 4. | sp3 and sp3 |
| 1. | 5375 × 10–3 g | 2. | 5.4 g |
| 3. | 5.38 g | 4. | 53.75 g |
Fluorine is known to be a stronger oxidizing agent than chlorine. Which of the following thermodynamic factors is the primary reason for this behavior?
| (a) |
The F–F bond has a low bond dissociation enthalpy. |
| (b) |
The fluoride ion (F⁻) has a high hydration enthalpy in aqueous solution. |
| (c) | The electron gain enthalpy of fluorine is less negative than that of chlorine. |
| (d) | Fluorine has a very small atomic size. |
| 1. | (a) and (b) only | 2. | (a) and (c) only |
| 3. | (a) and (d) only | 4. | (b) and (c) only |
| List-I (Complexes) | List-II (Type of isomer) | ||
| A. | [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 |
I. | Ionisation isomerism |
| B. | [Cr(NH3)6] [Co(CN)6] and [Cr(CN)6][Co(NH3)6] |
II. | Coordination isomerism |
| C. | [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 |
III. | Linkage isomerism |
| D. | [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]Cl2.H2O |
IV. | Solvate isomerism |
| (A) | (B) | (C) | (D) | |
| 1. | (III) | (I) | (II) | (IV) |
| 2. | (II) | (III) | (IV) | (I) |
| 3. | (III) | (II) | (I) | (IV) |
| 4. | (IV) | (III) | (II) | (I) |