| 1. | \(K^2_1=2K_2\) | 2. | \(K_2= \dfrac { K_1 }{2}\) |
| 3. | \(K_1=\dfrac 1{\sqrt K_2}\) | 4. | \(K_2=\dfrac 1{\sqrt K_1}\) |
| 1. | \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles. |
| 2. | All five \(\mathrm{P-Cl}\) bonds are identical in length. |
| 3. | \(\mathrm{PCl_5}\) exhibits sp3d hybridisation. |
| 4. | \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds. |
| 1. | Both the heat and work done will be greater than zero. |
| 2. | Heat absorbed will be less than zero and work done will be positive. |
| 3. | Work done will be zero and heat absorbed or evolved will also be zero. |
| 4. | Work done will be greater than zero and heat absorbed will remain zero. |

| 1. | \(\mathrm{Ce}^{4+} \) and \(\mathrm{Tb}^{4+}\) | 2. | \(\mathrm{La}^{3+} \) and \(\mathrm{Lu}^{3+}\) |
| 3. | \(\mathrm{Eu}^{2+} \) and \(\mathrm{Yb}^{2+}\) | 4. | \(\mathrm{Eu}^{2+} \) and \(\mathrm{Tb}^{4+}\) |
| 1. | \(\mathrm{CH}_3 \mathrm{COCl} \xrightarrow[\Delta]{\mathrm{H}_2 \mathrm{O}} \mathrm{CH}_3 \mathrm{COOH}\) |
| 2. | ![]() |
| 3. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{\oplus}]{\text { (i) } \mathrm{KMnO}_{4}/\mathrm{OH^{-} }} \mathrm{CH}_3 \mathrm{COOH}\) |
| 4. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH} \xrightarrow{\mathrm{CrO}_3-\mathrm{H}_2 \mathrm{SO}_4} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH}\) |
| 1. | Hexadentate ligand | 2. | Ambidentate ligand |
| 3. | Monodentate ligand | 4. | Bidentate ligand |