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| List-I (Transition metal/compound/complex) |
List-II (Catalytic Role) |
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| (a) | \(V_2O_5\) | (i) | Preparation of ammonia from \(N_2/H_2\) mixture |
| (b) | \(Fe\) | (ii) | Polymerisation of alkynes |
| (c) | \(PdCl_2\) | (iii) | Preparation of \(H_2SO_4\) from \(SO_2\) |
| (d) | \(Ni \) complex | (iv) | Oxidation of ethyne to ethanal |
| 1. | It has a trigonal pyramidal geometry with two lone pairs on Cl atom |
| 2. | It has T-shaped geometry with two lone pairs on Cl atom |
| 3. | It has a trigonal planar geometry with two lone pairs on Cl atom |
| 4. | It has T-shaped geometry with three lone pairs on Cl atom |
| List-I (Order of reaction) | List-II (Unit of rate constant) | ||
| A. | Zero order | I. | \(\mathrm{mol}^{-1} \mathrm{~L} \mathrm{~s}^{-1}\) |
| B. | First order | II. | \(\mathrm{mol}^{-2} \mathrm{~L}^2 \mathrm{~s}^{-1}\) |
| C. | Second order | III. | \(\mathrm {s}^{-1}\) |
| D. | Third order | IV. | \(\mathrm{mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}\) |
| 1. | A-IV, B-III, C-II, D-I |
| 2. | A-I, B-II, C-III, D-IV |
| 3. | A-IV, B-III, C-I, D-II |
| 4. | A-IV, B-II, C-I, D-III |

| 1. | Acetate, \(CH_3COO^-\) |
| 2. | Carbonate, \(\mathrm{CO}_3^{2-}\) |
| 3. | Sulphate, \(\mathrm{SO}_4^{2-}\) |
| 4. | Sulphide, \(S^{2-}\) |