| 1. | |
| 2. | Benzene, Cl2, anhydrous FeCl3 |
| 3. | Phenol, NaNO2, HCl, CuCl |
| 4. |
| 1. | Lithium is the strongest reducing agent among the alkali metals. |
| 2. | Alkali metals react with water to form their hydroxides. |
| 3. | The oxidation number of K in KO2 is +4. |
| 4. | Ionisation enthalpy of alkali metals decreases from top to bottom in the group. |
| 1. | 2. | ||
| 3. | 4. |
| 1. | \(\mathrm{2 {CuSO}_{4}({aq})+2 {Ag}({s}) → 2 {Cu}({s})+{Ag}_{2} {SO}_{4}({aq})} \) |
| 2. | \(\mathrm{{CuSO}_{4}({aq})+{Zn}({s})} \) \(\mathrm{→ {ZnSO}_{4}({aq})+{Cu}({s})} \) |
| 3. | \(\mathrm{{CuSO}_{4}({aq})+{Fe}({s})} \) \(\mathrm{→ {FeSO}_{4}({aq})+{Cu}({s})} \) |
| 4. | \(\mathrm{{FeSO}_{4}({aq})+{Zn}({s})} \) \(→ \mathrm{{ZnSO}_{4}({aq})+{Fe}({s})} \) |
| I: | The acidic strength of monosubstituted nitrophenol is higher than phenol because of electron withdrawing nitro group. |
| II: | o-Nitrophenol, m-nitrophenol and p-nitrophenol will have same acidic strength as they have one nitro group attached to the phenolic ring. |
| 1. | I is incorrect but II is correct. |
| 2. | Both I and II are correct. |
| 3. | Both I and II are incorrect. |
| 4. | I is correct but II is incorrect. |
| 1. | Both the boron atoms are sp2 hybridised. |
| 2. | There are two 3-centre-2-electron bonds. |
| 3. | The four terminal B-H bonds are 2-centre-2-electron bonds. |
| 4. | The four terminal hydrogen atoms and the two boron atoms lie in one plane. |
| Statement I | The boiling points of aldehydes and ketones are higher than hydrocarbons of comparable molecular masses because of weak molecular association in aldehydes and ketones due to dipole-dipole interactions. |
| Statement II | The boiling points of aldehydes and ketones are lower than the alcohols of similar molecular masses due to the absence of H-bonding. |
| 1. | Statement I is incorrect but Statement II is correct. |
| 2. | Both Statement I and Statement II are correct. |
| 3. | Both Statement I and Statement II are incorrect. |
| 4. | Statement I is correct but Statement II is incorrect. |
| Assertion (A): | ICl is more reactive than I₂. |
| Reason (R): | I-Cl bond is weaker than I-I bond. |
| 1. | (A) is False but (R) is True. |
| 2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 4. | (A) is True but (R) is False. |
| List-I (Products formed) |
List - II (Reaction of carbonyl compound with) |
||
| (A) | Cyanohydrin | (I) | NH₂OH |
| (B) | Acetal | (II) | RNH₂ |
| (C) | Schiff's base | (III) | Alcohol |
| (D) | Oxime | (IV) | HCN |
| (A) | (B) | (C) | (D) | |
| 1. | (IV) | (III) | (II) | (I) |
| 2. | (III) | (IV) | (II) | (I) |
| 3. | (II) | (III) | (IV) | (I) |
| 4. | (I) | (III) | (II) | (IV) |