| 1. | \(\text{A}\) and \(\text{D}\) | 2. | \(\text{B}\) and \(\text{E}\) |
| 3. | \(\text{E}\) and \(\text{D}\) | 4. | \(\text{B}\) and \(\text{C}\) |
| 1. | \(-\dfrac x9\) | 2. | \(-4x\) |
| 3. | \(-\dfrac 49x\) | 4. | \(-x\) |
| List-I (Process) | List-II (Conditions) | ||
| A. | Isothermal process | I. | No heat exchange |
| B. | Isochoric process | II. | Carried out at constant temperature |
| C. | Isobaric process | III. | Carried out at constant volume |
| D. | Adiabatic process | IV. | Carried out at constant pressure |
| 1. | \(\text { A-IV, B-II, C-III, D-I }\) | 2. | \(\text { A-I, B-II, C-III, D-IV }\) |
| 3. | \(\text { A-II, B-III, C-IV, D-I }\) | 4. | \(\text { A-IV, B-III, C-II, D-I }\) |
| 1. | Reaction has a tendency to go in the forward direction. |
| 2. | Reaction has a tendency to go in the backward direction. |
| 3. | Reaction has gone to completion in the forward direction. |
| 4. | Reaction is at an equilibrium. |
| List-I (Complex) | List-II (Type of isomerism) |
||
| A. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2}\) | I. | Solvate isomerism |
| B. | \(\mathrm{\left[{Co}\left({NH}_3\right)_5\left({SO}_4\right)\right] {Br}}\) | II. | Linkage isomerism |
| C. | \(\mathrm{\left[{Co}\left({NH}_3\right)_6\right]\left[{Cr}({CN})_6\right]}\) | III. | Ionization isomerism |
| D. | \(\mathrm{\left[{Co}\left({H}_2 {O}\right)_6\right] {Cl}_3}\) | IV. | Coordination isomerism |
| A. | A liquid evaporates to vapour. |
| B. | Temperature of a crystalline solid lowered from \(130~\text{K}\) to \(0~\text{K}.\) |
| C. | \(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\) |
| D. | \(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\) |
| 1. | \(\text { A, B and D }\) | 2. | \(\text { A, C and D }\) |
| 3. | \(\text { C and D }\) | 4. | \(\text { A and C }\) |
| 1. | \(\text { (i) } \mathrm{BH}_3\) | 2. | \(\text { (i) } \mathrm{BH}_3\) |
| \((ii) \mathrm{H}_2 \mathrm{O}_2 / \stackrel{\ominus}{\mathrm{OH}}\) | \((ii) \mathrm{H}_2 \mathrm{O}_2 / \stackrel{\ominus}{\mathrm{OH}}\) | ||
| \(\text { (iii) } \mathrm{P C C}\) | \(\text { (iii) alk. } \mathrm{KMnO}_4\) | ||
| \(\text { (iv) } \mathrm{H}_3 \mathrm{O}^{+}\) | |||
| 3. | \(\text { (i) } \mathrm{H}_2 \mathrm{O} / \mathrm{H}^{+}\) | 4. | \(\text { (i) } \mathrm{H}_2 \mathrm{O} / \mathrm{H}^{+}\) |
| \(\text { (ii) } \mathrm{P C C}\) | \(\text { (ii) } \mathrm{CrO}_3\) |
| List-I (Reaction) |
List-II (Reagents/ Condition) |
||
| A. | ![]() |
I. | ![]() |
| B. | ![]() |
II. | \(\mathrm{CrO}_3\) |
| C. | ![]() |
III. | \(\begin{aligned} & \mathrm{KMnO}_4 \\ & \mathrm{KOH}, \Delta \end{aligned}\) |
| D. | ![]() |
IV. | \(\mathrm{(i) \mathrm{O}_3\\ (ii) \mathrm{Zn}-\mathrm{H}_2 \mathrm{O}}\) |
| 1. | \(\text { A-III, B-I, C-II, D-IV }\) |
| 2. | \(\text { A-IV, B-I, C-II, D-III }\) |
| 3. | \(\text { A-I, B-IV, C-II, D-III }\) |
| 4. | \(\text { A-IV,B-I, C-III, D-II }\) |
| 1. | \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\) |
| 2. | \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\) |
| 3. | \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\) |
| 4. | \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\) |