Crystal field splitting energy for high spin d4 octahedral complex is:
1. – 1.2 \(\Delta_{0}\) 2. – 0.6 \(\Delta_{0}\)
3. – 0.8 \(\Delta_{0}\) 4. –1.6 \(\Delta_{0}\)
Subtopic:  VBT, CFT & their Limitations |
 77%
Level 2: 60%+
NEET - 2013
Hints

Arrange the following in increasing order of stability:
(a) \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}-\mathrm{CH}_2-\mathrm{CH}_3 \) (b) \(\left(\mathrm{CH}_3\right)_3 \stackrel{\oplus}{\mathrm{C}} \)
(c) \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}\mathrm{H} \) (d) \(\mathrm{CH}_3 \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_2\)
(e) \( \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_3 \)
 
1. e < d < c < a < b 2. d < e < c < a < b
3. a < e < d < c < b 4. e < d < c < b < a
Subtopic:  Reaction Intermediates ; Preparation & Properties |
 74%
Level 2: 60%+
NEET - 2013
Hints

Consider the half-cell reduction reaction:
\(\text{Mn}^{2+}+2e^-\rightarrow \text{Mn},\ E^{0}= -1.18~ \text V \) 
\(\text{Mn}^{2+}\rightarrow \text{Mn}^{3+}+e^-,\ E^{0}= -1.51~ \text V \)

The \(E^{0}\) for the reaction \(\mathrm{3\ Mn^{2+}\rightarrow Mn^{0}+2Mn^{3+} }\) and possibility of the forward reaction are respectively:
 
1. –4.18 V and Yes 2. +0.33 V and Yes
3. +2.69 V and No 4. –2.69 V and No
Subtopic:  Electrode & Electrode Potential |
 56%
Level 3: 35%-60%
NEET - 2013
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How many grams of cobalt metal will be deposited when a solution of cobalt (II) chloride is electrolyzed with a current of 10 amperes for 109 minutes?
(Given: 1 Faraday = 96,500 C; Atomic mass of Co = 59 u)
1. 4.0 2. 20.0
3. 40.0 4. 0.66
Subtopic:  Faraday’s Law of Electrolysis |
 71%
Level 2: 60%+
NEET - 2013
Hints

In a particular isomer of [Co(NH3)4Cl2]°, the Cl–Co–Cl angle is 90°, and the isomer is known as:
1. Optical isomer 2. Cis-isomer
3. Position isomer 4. Linkage isomer
Subtopic:  Isomerism in Coordination Compounds |
 75%
Level 2: 60%+
NEET - 2013
Hints

Which one of the following statements is not true?
 
1. Clean water would have a BOD value of 5 ppm.
2. Fluoride deficiency in drinking water is harmful. Soluble fluoride is often used to bring its concentration upto 1 ppm.
3. When the pH of rainwater is higher than 6.5, it is called acid rain.
4. Dissolved Oxygen (DO) in cold water can reach a concentration upto 10 ppm.
Subtopic:  Air Pollution - Acid Rain | Water Pollution - Water Pollution & Portable Water |
 69%
Level 2: 60%+
NEET - 2013
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Calculate the heat released when 5 L of a gaseous mixture of methane (CH₄) and propane (C₃H₈) is completely combusted at 0°C and 1 atm, given that 16 L of oxygen is consumed.
Enthalpy of combustion: ΔHc(CH₄) = 890 kJ mol⁻¹, ΔHc(C₃H₈) = 2220 kJ mol⁻¹.
 
1. 38 2. 317
3. 477 4. 32
Subtopic:  Thermochemistry |
 64%
Level 2: 60%+
NEET - 2013
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The hybridisation of benzyl carbonium ion   is:
1. sp2 2. spd2
3. sp2d 4. sp3
Subtopic:  Hybridisation & Structure of Carbon Compounds |
 84%
Level 1: 80%+
NEET - 2013
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The pair of species that has the same bond order in the following is:
1. CO, NO+ 2. NO–, CN–
3. O2, N2 4. O2, B2
Subtopic:  M.O.T |
 84%
Level 1: 80%+
NEET - 2013
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Find the energy absorbed per mole of photons according to the law of photochemical equivalence using:

E = Nₐhc/λ

Given:

h = 6.62 × 10⁻²⁷ erg s
c = 3 × 10¹⁰ cm s⁻¹
Nₐ = 6.02 × 10²³ mol⁻¹

 
1. \({{1.196\times 10^{8}}\over{\lambda}}\) 2. \({{2.859\times 10^{5}}\over{\lambda}}\)
3. \({{2.859\times 10^{16}}\over{\lambda}}\) 4. \({{1.196\times 10^{16}}\over{\lambda}}\)
Subtopic:  Electromagnetic Radiation |
 63%
Level 2: 60%+
NEET - 2013
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