| 1. | – 1.2 \(\Delta_{0}\) | 2. | – 0.6 \(\Delta_{0}\) |
| 3. | – 0.8 \(\Delta_{0}\) | 4. | –1.6 \(\Delta_{0}\) |
| (a) | \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}-\mathrm{CH}_2-\mathrm{CH}_3 \) | (b) | \(\left(\mathrm{CH}_3\right)_3 \stackrel{\oplus}{\mathrm{C}} \) |
| (c) | \(\left(\mathrm{CH}_3\right)_2 \stackrel{\oplus}{\mathrm{C}}\mathrm{H} \) | (d) | \(\mathrm{CH}_3 \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_2\) |
| (e) | \( \stackrel{\oplus}{\mathrm{C}}\mathrm{H}_3 \) | ||
| 1. | e < d < c < a < b | 2. | d < e < c < a < b |
| 3. | a < e < d < c < b | 4. | e < d < c < b < a |
| 1. | –4.18 V and Yes | 2. | +0.33 V and Yes |
| 3. | +2.69 V and No | 4. | –2.69 V and No |
| 1. | 4.0 | 2. | 20.0 |
| 3. | 40.0 | 4. | 0.66 |
| 1. | Optical isomer | 2. | Cis-isomer |
| 3. | Position isomer | 4. | Linkage isomer |
| 1. | Clean water would have a BOD value of 5 ppm. |
| 2. | Fluoride deficiency in drinking water is harmful. Soluble fluoride is often used to bring its concentration upto 1 ppm. |
| 3. | When the pH of rainwater is higher than 6.5, it is called acid rain. |
| 4. | Dissolved Oxygen (DO) in cold water can reach a concentration upto 10 ppm. |
| 1. | 38 | 2. | 317 |
| 3. | 477 | 4. | 32 |
| 1. | sp2 | 2. | spd2 |
| 3. | sp2d | 4. | sp3 |
| 1. | CO, NO+ | 2. | NO–, CN– |
| 3. | O2, N2 | 4. | O2, B2 |
Find the energy absorbed per mole of photons according to the law of photochemical equivalence using:
E = Nₐhc/λ
Given:
h = 6.62 × 10⁻²⁷ erg s
c = 3 × 10¹⁰ cm s⁻¹
Nₐ = 6.02 × 10²³ mol⁻¹
| 1. | \({{1.196\times 10^{8}}\over{\lambda}}\) | 2. | \({{2.859\times 10^{5}}\over{\lambda}}\) |
| 3. | \({{2.859\times 10^{16}}\over{\lambda}}\) | 4. | \({{1.196\times 10^{16}}\over{\lambda}}\) |