What is the pH of a solution prepared by mixing equal volumes (50 mL each) of 0.10 M sodium acetate and 0.01 M acetic acid?
[Given pKa of CH3COOH = 4.57]
1. 2.57
2. 5.57
3. 3.57
4. 4.57
| 1. | \(p_i=\chi_ip^o_i,\) where \(\chi_i=\) mole fraction of \(i^\text{th}\) gas in a gaseous mixture \(p_{i}^{o}=\) pressure of \(i^\text{th}\) gas in a pure state |
| 2. | \(\mathrm{p}=\mathrm{p}_{1}+\mathrm{p}_{2}+\mathrm{p}_{3} \) |
| 3. | \(\mathrm{p}=\mathrm{n}_{1} \frac{\mathrm{RT}}{\mathrm{V}}+\mathrm{n}_{2} \frac{\mathrm{RT}}{\mathrm{V}}+\mathrm{n}_{3} \frac{\mathrm{RT}}{\mathrm{V}}\) |
| 4. | \(\mathrm{p}_{i}=\chi_{i} \mathrm{p} \), where \(\mathrm{p}_{i}=\) partial pressure of \(i^\text{th}\) gas \(\chi_i=\) mole fraction of \(i^\text{th}\) gas in a gaseous mixture |
| 1. | Enzymes are very specific for a particle reaction and substrate. |
| 2. | Enzymes are biocatalysts. |
| 3. | Like chemical catalysts, enzymes reduce the activation energy of bio processes. |
| 4. | Enzymes are polysaccharides. |
| List-I | List-II | ||
| (a) | Li | (i) | absorbent for carbon dioxide |
| (b) | Na | (ii) | electrochemical cells |
| (c) | KOH | (iii) | coolant in fast breeder reactors |
| (d) | Cs | (iv) | photoelectric cell |
| (a) | (b) | (c) | (d) | |
| 1. | (ii) | (iii) | (i) | (iv) |
| 2. | (iv) | (i) | (iii) | (ii) |
| 3. | (iii) | (iv) | (ii) | (i) |
| 4. | (i) | (iii) | (iv) | (ii) |
| Statement I: | Primary aliphatic amines react with HNO2 to give unstable diazonium salts. |
| Statement II: | Primary aromatic amines react with HNO2 to form diazonium salts which are stable even above 300 K. |
| 1. | Statement I is incorrect but Statement II is correct |
| 2. | Both Statement I and II are correct |
| 3. | Both Statement I and II are incorrect |
| 4. | Statement I is correct but Statement II is incorrect |
| 1. | |
| 2. | Benzene, Cl2, anhydrous FeCl3 |
| 3. | Phenol, NaNO2, HCl, CuCl |
| 4. |
| 1. | Lithium is the strongest reducing agent among the alkali metals. |
| 2. | Alkali metals react with water to form their hydroxides. |
| 3. | The oxidation number of K in KO2 is +4. |
| 4. | Ionisation enthalpy of alkali metals decreases from top to bottom in the group. |
| 1. | 2. | ||
| 3. | 4. |
| 1. | \(\mathrm{2 {CuSO}_{4}({aq})+2 {Ag}({s}) → 2 {Cu}({s})+{Ag}_{2} {SO}_{4}({aq})} \) |
| 2. | \(\mathrm{{CuSO}_{4}({aq})+{Zn}({s})} \) \(\mathrm{→ {ZnSO}_{4}({aq})+{Cu}({s})} \) |
| 3. | \(\mathrm{{CuSO}_{4}({aq})+{Fe}({s})} \) \(\mathrm{→ {FeSO}_{4}({aq})+{Cu}({s})} \) |
| 4. | \(\mathrm{{FeSO}_{4}({aq})+{Zn}({s})} \) \(→ \mathrm{{ZnSO}_{4}({aq})+{Fe}({s})} \) |
| I: | The acidic strength of monosubstituted nitrophenol is higher than phenol because of electron withdrawing nitro group. |
| II: | o-Nitrophenol, m-nitrophenol and p-nitrophenol will have same acidic strength as they have one nitro group attached to the phenolic ring. |
| 1. | I is incorrect but II is correct. |
| 2. | Both I and II are correct. |
| 3. | Both I and II are incorrect. |
| 4. | I is correct but II is incorrect. |