1.00 g of non-electrolyte solute (molar mass 250 g mol-1) was dissolved in 51.2 g of benzene. If the freezing point depression constant, Kf of benzene is 5.12 mol-1 kg K, the freezing point of benzene will be lowered by:
1. 0.4 K
2. 0.3 K
3. 0.5 K
4. 0.2 K
Find the pair that constitutes a buffer solution.
1. HNO₂ and NaNO₂The hydrogen ion concentration of a 10-8 M HCl aqueous solution at 298 K (Kw = 10-14) is:
1. \(1 . 0 \times \left(10\right)^{- 6}\) \(M\)
2. \(1 . 0525 \times \left(10\right)^{- 7}\) \(M\)
3. \(9 . 525 \times \left(10\right)^{- 8}\) \(M\)
4. \(1 . 0 \times \left(10\right)^{- 8}\) \(M\)
A solution of acetone in ethanol:
| 1. | Shows a negative deviation from Raoult's law |
| 2. | Shows a positive deviation from Raoult's law |
| 3. | Behaves like a near-ideal solution |
| 4. | Obeys Raoult's law |
For the hypothetical electrochemical cell given below:
A | A⁺(x M) || B⁺(y M) | B .
The measured cell emf is +0.20 V. Find the overall cell reaction.
1. A+ + B → A + B+
2. A+ + e- → A ; B+ + e- → B
3. The cell reaction cannot be predicted.
4. A + B+ → A+ + B
Ethylene oxide when treated with Grignard reagent yields:
1. secondary alcohol
2. tertiary alcohol
3. cyclopropyl alcohol
4. primary alcohol
During osmosis, the flow of water through a semi-permeable membrane is:
| 1. | From a solution having higher concentration only. |
| 2. | From both sides of the semi-permeable membrane with equal flow rates. |
| 3. | From both sides of the semi-permeable membrane with unequal flow rates. |
| 4. | From a solution having lower concentration only. |
Which of the following compounds has a higher basic character than aniline?
1. Diphenylamine
2. Triphenylamine
3. p-nitroaniline
4. Benzylamine
Find the molecule in which not all the bonds are equal.
| 1. | ClF3 | 2. | BF3 |
| 3. | AlF3 | 4. | NF3 |
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:
| 1. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction |
| 2. | In NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions |
| 3. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions |
| 4. | In NH3 the atomic dipole and the bond dipole is in opposite directions whereas in NF3 these are in the same directions |