The alkali metals form salt-like hydrides by direct synthesis at elevated temperatures. The thermal stability of these hydrides decreases in which of the following orders?

1. CsH > RbH > KH > NaH > LiH

2. KH > NaH > LiH > CsH > RbH

3. NaH > LiH > KH > RbH > CsH

4. LiH > NaH > KH > RbH > CsH

Subtopic:  Chemical Properties |
 66%
Level 2: 60%+
AIPMT - 2008
Hints

Which one of the following arrangements does not give the correct picture of the trends indicated against it?
1. F2> Cl2> Br2> I2 : Oxidising power
2. F<Cl>Br>I : Electron gain enthalpy
3. F2> Cl2> Br2> I2 : Bond dissociation energy
4. F> Cl > Br > I : Electronegativity

Subtopic:  Ionization Energy (IE) | Electronegativity | Electron Affinity (EA) |
 66%
Level 2: 60%+
AIPMT - 2008
Hints

The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 52%
Level 3: 35%-60%
AIPMT - 2008
Hints

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For the above-given reaction, A (Predominantly) is:

1. 2.
3. 4.
Subtopic:  Reaction Intermediates |
 74%
Level 2: 60%+
AIPMT - 2008
Hints

The following compounds are given for reference
(1) CH3-CH2–
(2) H2C=CH–
(3) HC≡C– 

The increasing order of basic strength is:
1. (2)>(1)>(3)
2. (3) >(2) >(1)
3. (1) >(3) >(2)
4. (1) >(2)>(3)

Subtopic:  Hybridisation & Structure of Carbon Compounds |
 70%
Level 2: 60%+
AIPMT - 2008
Hints

Which of the following statements is not correct?
1. The fraction of the total volume occupied by
die atoms in a primitive cell is 0.48
2. Molecular solids are generally volatile
3. The number of carbon atoms in a unit
cell of a diamond is 8
4. The number of Bravais lattices in which a
crystal can be categorized is 14

Subtopic:  Density & Packing Fraction |
 65%
Level 2: 60%+
AIPMT - 2008
Hints

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If 'a’ stands for the edge length of the cubic systems: simple cubic, body-centered cubic, and face-centered cubic, then the ratio of radii of the spheres in these systems will be respectively: 

1. 12a : 34a : 122a

2. 12a : 3a : 12a

3. 12a : 32a : 22a

4. 1a : 3a : 2a

Subtopic:  Voids, Radius Ratio & Coordination Number |
 85%
Level 1: 80%+
AIPMT - 2008
Hints

The rate constants k1 and k2 for two different reactions are 1016. e-2000/T and 1015. e-1000/T, respectively. The temperature at which k1= k2 is:

1. 1000 K

2. 20002.303 K

3. 2000 K

4. 10002.303 K

Subtopic:  Arrhenius Equation |
 62%
Level 2: 60%+
AIPMT - 2008
Hints

The volume of oxygen gas (O2) needed to completely burn 1 L of propane gas (C3H8)  (both O2 & propane measured at 0°C and 1 atm) will be:
1. 7 L
2. 6 L
3. 5 L
4. 10 L

Subtopic:  Equation Based Problem |
 78%
Level 2: 60%+
AIPMT - 2008
Hints
Links

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Identify the correct increasing order of O–N–O bond angle among the following species:

1. NO₂⁻ < NO₂⁺ < NO₂
2. NO₂⁻ < NO₂ < NO₂⁺
3. NO₂⁺ < NO₂ < NO₂⁻
4. NO₂⁺ < NO₂⁻ < NO₂

Subtopic:  V.S.E.P.R & V.B.T |
 72%
Level 2: 60%+
AIPMT - 2008
Hints