Which is the correct order of increasing energy of the listed orbitals in the atom of titanium?
1. 3s 4s 3p 3d
2. 4s 3s 3p 3d
3. 3s 3p 3d 4s
4. 3s 3p 4s 3d
The reaction of a carbonyl compound with one of the following reagents involves nucleophilic addition followed by the elimination of water. The reagents are:
| 1. | A Grignard reagent. |
| 2. | Hydrazine in the presence of a feebly acidic solution. |
| 3. | Hydrocyanic acid. |
| 4. | Sodium hydrogen sulphite. |
The variation of the boiling point of the hydrogen halides is in the order HF > HI > HBr > HCl.
The higher boiling point of hydrogen fluoride is explained as:
| 1. | The electronegativity of flourine is much higher than other elements in group |
| 2. | There is strong hydrogen bonding between HF molecules |
| 3. | The bond energy of HF molecules is greater than in other hydrogen halides |
| 4. | The effect of nuclear shielding is much reduced in flourine which polarizes the HF molecule |
The IUPAC name of complex ion, [Fe(CN)6]3- is:
| 1. | Hexacyanoiron(III) ion | 2. | Hexacyanitoferrate(III) ion |
| 3. | Tricynoferrate(III) ion | 4. | Hexacyanidoferrate(III) ion |
Mark the reaction that does not yield aniline from the given options:
| 1. | Hydrolysis of phenyl isocyanide with an acidic solution |
| 2. | Degradation of benzamide with bromine in alkaline solution |
| 3. | Reduction of nitrobenzene with H2/Pd in ethanol |
| 4. | Treatment of potassium salt of phthalimide with chlorobenzene followed by hydrolysis in an aqueous NaOH solution |
The equilibrium constant for the reaction:
N2(g) + O2 (g) ⇄ 2NO(g) is K.What will be the equilibrium constant for the reaction: \(\frac{1}{2}\)N2(g) + \(\frac{1}{2}\)O2(g) ⇄ NO(g)?
1.
2.
3. K
4.
The strong reducing behaviour of H3PO2 is due to:
1. Presence of one -OH group and two P-H bonds.
2. High electron gain enthalpy of phosphorus.
3. High oxidation state of phosphorus.
4. Presence of two -OH groups and one P-H bond.
2,3-dimethyl-2-butene can be prepared by heating which of the following compounds with a strong acid?
1.
2.
3.
4.
Aqueous solution of which of the following compounds is the best conductor of electric current?
| 1. | Acetic acid, \(\mathrm{C_{2} H_{4} O_{2}}\) | 2. | Hydrochloric acid, \(\mathrm{HCl}\) |
| 3. | Ammonia, \(\mathrm{N H_{3}}\) | 4. | Fructose, \(\mathrm{C_{6} H_{12} O_{6}}\) |
The vacant space in the BCC lattice cell is:
1. 26%
2. 48%
3. 23%
4. 32%