A complex ion among the following can absorb visible light is:
(At. no. Zn = 30, Sc = 21, Ti = 22, Cr = 24)
1. [Sc(H2O)3(NH3)3]3+
2. [Ti(en)2 (NH3)2]4+
3. [Cr(NH3)6]3+
4. [Zn(NH3)6]2+
Calculate the specific rate constant of the reaction if the half-life period of a first-order reaction is 1386 s?
1.
2.
3.
4.
Phenol in a set of reactions (as captured below) yielded a product Z.
\(\text{Phenol}\ \xrightarrow{\text{Zn Dust}}\ \text{X}\ \xrightarrow[\text{Anhy. }{AlCl_3}]{CH_3Cl}\ Y\)
\( Y\ \xrightarrow[KMnO_4]{\text{Alkaline}}\ Z\)
The structure of the product Z would be:
| 1. | Toluene | 2. | Benzaldehyde |
| 3. | Benzoic acid | 4. | Benzene |
Copper crystallizes in a face-centered cubic lattice with a unit cell length of 361 pm. The radius of the copper atom is:
1. 128 pm
2. 157 pm
3. 181 pm
4. 108 pm
For the reaction, A + B → products, it is observed that-
(1) On doubling the initial concentration of A only, the rate of reaction is also doubled and
(2) On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in the rate of the reaction.
The rate of this reaction is given by:
1.
2.
3.
4.
According to the MO theory, which of the following lists ranks the nitrogen species in terms of increasing bond order?
1.
2.
3.
4.
The correct state of hybridisation of C2, C3, C5 and C6 of the hydrocarbon
is in the sequence:
1. sp, sp3, sp2 and sp3
2. sp3, sp2, sp2 and sp
3. sp, sp2, sp2 and sp3
4. sp, sp2, sp3 and sp2
Among the following which is the strongest oxidising agent?
1.
2.
3.
4.
The molar conductance of solution of a weak monobasic acid is 8.0 ohm-1 cm2 and at infinite dilution is 400 ohm-1 cm2. The dissociation constant of this acid is:
| 1. | \(1.25 \times10^{-5}\) | 2. | \(1.25 \times10^{-6}\) |
| 3. | \(6.25 \times10^{-4}\) | 4. | \(1.25 \times10^{-4}\) |
Structures of some common polymers are given. The incorrect match is:
| 1. | Teflon | |
| 2. | Neoprene | |
| 3. | Terylene | |
| 4. | Nylon 66 |