Which one of the following species has a plane triangular shape?
| 1. | \(\mathrm N_3^-\) | 2. | \(\mathrm {N O}_{3}^{-}\) |
| 3. | \(\mathrm {N O}_{2}^-\) | 4. | \(\mathrm {C O}_{2}\) |
The acidity of diprotic acids in aqueous solution increases in the order:
1. H2S < H2Se < H2Te
2. H2Se < H2S < H2Te
3. H2Te < H2S < H2Se
4. H2Se < H2Te < H2S
(a) H2O2 + O3 → H2O + 2O2
(b) H2O2 + Ag2O → 2Ag + H2O + O2
The role of hydrogen peroxide in the above reactions is respectively:
| 1. | Oxidizing in (a) and reducing in (b) |
| 2. | Reducing in (a) and oxidizing in (b) |
| 3. | Reducing in (a) and (b) |
| 4. | Oxidizing in (a) and (b) |
Artificial sweetener which is stable under cold conditions only is:
1. Saccharine
2. Sucralose
3. Aspartame
4. Alitame
In acidic medium, H2O2 changes Cr2O7–2 to CrO5 which has two (–O – O–) bonds.
The oxidation state of Cr in CrO5 is:
1. +5
2. +3
3. +6
4. -10
The reaction of aqueous KMnO4 with H2O2 in acidic condition gives:
1.
2.
3.
4.
Among the following complexes, the one which shows zero crystal field stabilization energy (CFSE) is:
| 1. | 2. | ||
| 3. | 4. |
An ion that has magnetic moment 2.83 BM is:
(Atomic Number: Ti=22, Cr=24, Mn=25, Ni=28)
| 1. | 2. | ||
| 3. | 4. |
|
An anticancer agent among the following is:
| 1. | \(\text { mer} - \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}\right] \) | 2. | \(\text { cis -} \left[\mathrm{PtCl}_2\left(\mathrm{NH}_3\right)_2\right] \) |
| 3. | \(\text {cis -} \mathrm{K}_2\left[\mathrm{Pt} \mathrm{Cl}_2 \mathrm{Br}_2\right] \) | 4. | \(\mathrm{NH}_2 \mathrm{CoCl}_4\) |
The reason for the lanthanoid contraction is:
1. negligible screening effect of 'f' orbitals.
2. increasing nuclear charge.
3. decreasing nuclear charge.
4. decreasing screening effect.