Calculate the mass of silver (atomic mass = 108) deposited by the same quantity of electricity that
liberates 5600 mL of O₂ at STP.

1. 5.4 g

2. 10.8 g

3. 54.0 g

4. 108.0 g

Subtopic:  Faraday’s Law of Electrolysis |
 55%
Level 3: 35%-60%
AIPMT - 2014
Hints

Which of the following statements is correct for the spontaneous adsorption of a gas?

1. ∆ S is negative and therefore,  ∆ H should be highly positive
2. ∆ S is negative and therefore,  ∆ H should be highly negative
3. ∆ S is positive and therefore,  ∆ H should be negative
4. -∆ S is positive and therefore,  ∆ H should also be highly positive

Subtopic:  Adsorption and Absorption |
 55%
Level 3: 35%-60%
AIPMT - 2014
Hints

Find the condition that shifts the following exothermic equilibrium towards the formation of NH₃:

N₂(g) + 3H₂(g) ⇌ 2NH₃(g) + heat

1. Increasing the concentration of NH₃
2. Decreasing the pressure
3. Decreasing the concentration of H₂
4. Increasing the pressure and decreasing the temperature

Subtopic:  Le Chatelier's principle |
 86%
Level 1: 80%+
AIPMT - 2014
Hints

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For the reaction:
\(\mathrm{X}_2 \mathrm{O}_4(l) \rightarrow 2 \mathrm{XO}_2(g)\)
with the given values \(\Delta U = 2.1 \, \text{kcal}\) and \(\Delta S = 20 \, \text{cal K}^{-1}\) at \(300 \, \text{K}\), what is the value of \(\Delta G\)?

1. +2.7 kcal
2. –2.7 kcal
3. +9.3 kcal
4. –9.3 kcal

Subtopic:  Gibbs Energy Change |
 78%
Level 2: 60%+
AIPMT - 2014
Hints

For a given exothermic reaction, Kp and Kp’ are the equilibrium constants at temperatures T1 and T2 respectively. Assuming that the heat of reaction is constant in temperatures range between T1 and T2, it is readily observed that:
1. Kp>Kp'
2. Kp<Kp'
3. Kp=Kp'
4. Kp=1Kp'

Subtopic:  Kp, Kc & Factors Affecting them |
 54%
Level 3: 35%-60%
AIPMT - 2014
Hints

Which of the following represents the correct order of ionic radii?

1. H⁻ > H⁺ > H
2. Na⁺ > F⁻ > O²⁻
3. F⁻ > O²⁻ > Na⁺
4. N³⁻ > Mg²⁺ > Al³⁺
Subtopic:  Atomic Size |
 82%
Level 1: 80%+
AIPMT - 2014
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When \(1.0\text{ g}\) of magnesium (\(\text{Mg}\)) is reacted with \(0.56\text{ g}\) of oxygen (\(\text{O}_2\)) in a closed container, determine the reactant left in excess and calculate the mass of the excess reactant remaining after the reaction is complete: (At. wt. Mg = 24; O = 16)

1. Mg, 0.16 g 2. O2, 0.16 g
3. Mg, 0.44 g 4. O2, 0.28 g
Subtopic:  Moles, Atoms & Electrons |
 61%
Level 2: 60%+
AIPMT - 2014
Hints

The pair of compounds that can exist together is:

1. FeCl3, SnCl2

2. HgCl2, SnCl2

3. FeCl2, SnCl2

4. FeCl3, Kl

Subtopic:  d-Block Elements- Properties & Uses |
 51%
Level 3: 35%-60%
AIPMT - 2014
Hints

Which of the following ionic species is isoelectronic with \(\mathrm{Be^{2+}}\)?

1. H+ 2. Li+
3. Na+ 4. Mg2+
Subtopic:  Electronic Configuration |
 92%
Level 1: 80%+
AIPMT - 2014
Hints

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A molecule among the following that has the maximum dipole moment is:

1. \(\mathrm{CO_2}\) 2. \(\mathrm{CH_4}\)
3. \(\mathrm{NH_3}\) 4. \(\mathrm{NF_3}\)
Subtopic:  Polarity |
 81%
Level 1: 80%+
AIPMT - 2014
Hints
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