| Assertion (A): | The metal carbon bond in metal carbonyls possesses both \(\sigma\) and \(\pi\) character. |
| Reason (R): | The ligand to metal bond is a \(\pi\) bond and metal to ligand bond is a \(\sigma\) bond. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| 1. | Aniline, NaNO2 + HCl, H2O, heating |
| 2. | Cumene, O2, H3O+ |
| 3. | |
| 4. |
| List-I | List-II |
| (a) Biochemical oxygen demand | (i) Oxidising mixture |
| (b) Photochemical smog | (ii) Polar stratospheric cloud |
| (c) Classical smog | (iii) Organic matter in water |
| (d) Ozone layer depletion | (iv) Reducing mixture |
| (a) | (b) | (c) | (d) | |
| 1. | (i) | (iv) | (ii) | (iii) |
| 2. | (iii) | (iv) | (i) | (ii) |
| 3. | (iii) | (i) | (iv) | (ii) |
| 4. | (iv) | (iii) | (ii) | (i) |
| 1. | |
| 2. | |
| 3. | |
| 4. |
| Statement I: | Cr2+ is oxidising agent and Mn3+ is a reducing agent in nature. |
| Statement II: | Sc3+ compounds are repelled by the applied magnetic field. |
| 1. | Both I and II are correct. |
| 2. | Both I and II are incorrect. |
| 3. | I is correct but II is incorrect. |
| 4. | I is incorrect but II is correct. |
| 1. | 0.36 | 2. | 3.6 × 10–2 |
| 3. | 3.6 × 10–3 | 4. | 3.6 |
| 1. | –200.27 kJ mol–1 | 2. | –212.27 kJ mol–1 |
| 3. | –212.27 J mol–1 | 4. | –200.27 J mol–1 |
| 1. | 2. | ||
| 3. | 4. |