In which of the following the hydration energy is higher than the lattice energy?

1. BaSO4

2. MgSO4

3. CaSO4

4. SrSO4

Subtopic:  Chemical Properties | Compounds of Ca and Na -Preparations, Properties & Uses |
 74%
Level 2: 60%+
AIPMT - 2007
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Which compound, upon reduction with lithium aluminium hydride, yields a secondary amine?

1. Nitroethane

2. Methylisocyanide

3. Acetamide

4. Methyl cyanide

Subtopic:  Identification of Primary, Secondary & Tertiary Amines | Cyanides & Isocyanides |
 83%
Level 1: 80%+
AIPMT - 2007
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Consider the following reactions: 

(i) H+(aq) + OH-(aq) → H2O(l)
ΔH = -x1 kJmol-1
(ii) H2(g) + 1/2O2(g) → H2O(l)
ΔH = -x2 kJmol-1
(iii) CO2(g) + H2(g) → CO (g) + H2O(l)
ΔH = -x3 kJmol-1
(iv) C2H2(g) + 5/2O2(g) →  2CO2 + H2O(l)
ΔH = -x4 kJmol-1


Enthalpy of formation of H2O(l) is :

1. -x3 kJ mol-1

2. -x4 kJ mol-1

3. -x1 kJ mol-1

4. -x2 kJ mol-1

Subtopic:  Thermochemistry |
 77%
Level 2: 60%+
AIPMT - 2007
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The bond energy of H—H and Cl-Cl is 430 kJ
mol-1 and 240 kJ mol-1 respectively and ΔHf for HCl is -90 kJ mol-1. The bond enthalpy of HCl is:

1. 290 kJ mol-1

2. 380 kJ mol-1

3. 425 kJ mol-1

4. 245 kJ mol-1

Subtopic:  Thermochemistry |
 63%
Level 2: 60%+
AIPMT - 2007
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Reduction of aldehydes and ketones into hydrocarbons using amalgam and conc. HCl is called:

1. Clemmensen reduction

2. Cope reduction

3. Dow reduction

4. Wolff-Kishner reduction

Subtopic:  Aldehydes & Ketones: Preparation & Properties | Name Reaction |
 88%
Level 1: 80%+
AIPMT - 2007
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Which one of the following anions is present in the chain structure silicates?

1. Si2O76-

2. (Si2O52-)n

3. (SiO32-)n

4. SiO44-

Subtopic:  Properties of Structure of SiO2 & Other Compounds |
Level 3: 35%-60%
AIPMT - 2007
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The fraction of total volume occupied by the atoms present in a simple cube is:

1. π6

2. π32

3. π42

4. π4

Subtopic:  Density & Packing Fraction |
 80%
Level 1: 80%+
AIPMT - 2007
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For the following: 
(i) I- 
(ii) Cl- 
(iii) Br- 
The increasing order of nucleophilicity would be:

1. I-<Br-<Cl-

2. Cl-<Br-<I- 

3. I- <Cl-<Br-

4. Br-<Cl-<I-

Subtopic:  Mechanism of Reactions |
 65%
Level 2: 60%+
AIPMT - 2007
Hints

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

1. HOCl<HOClO<HOClO2<HOClO3

2. HOClO<HOCl<HOClO3<HOClO2

3. HOClO2<HOClO3<HOClO<HOCl

4. HOClO3<HOClO2<HOClO<HOCl

Subtopic:  Acids & Bases - Definitions & Classification |
 88%
Level 1: 80%+
AIPMT - 2007
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The product formed in the below-mentioned reaction is:

1.    
2.  
3.  
4.   

Subtopic:  Alcohols: Preparation & Properties | Ethers: Preparation & Properties, Uses |
 72%
Level 2: 60%+
AIPMT - 2007
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