The stability of carbanions in the following:
 
is in the order of:

1.  (1) > (2) > (3) > (4)

2.  (2) > (3) > (4) > (1)

3.  (4) > (2) > (3) > (1)

4.  (1) > (3) > (2) > (4)

Subtopic:  Reaction Intermediates ; Preparation & Properties |
 61%
Level 2: 60%+
AIPMT - 2008
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Bond dissociation enthalpy of H2, Cl2, and HCl are 434, 242, and 431 kJ mol1 respectively. Enthalpy of formation of HCl is:
1. 93 kJ mol-1
2. - 245 kJ mol-1
3. -93 kJ mol-1
4. 245 kJ mol-1
Subtopic:  Thermochemistry |
 66%
Level 2: 60%+
AIPMT - 2008
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The dissociation equilibrium of a gas AB2 can be represented as 
 2AB2(g) ⇋ 2AB(g) + B2(g) 
The degree of dissociation is ‘x’ and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant KP and total pressure p is:
1. (2KP/p)
2. (2Kp /p)1/3
3. (2KP/p)1/2
4. (KP/P)

Subtopic:  Kp, Kc & Factors Affecting them |
 69%
Level 2: 60%+
AIPMT - 2008
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An amine that acts as a hormone is:
1. Thyroxine 2. Oxypurin
3. Insulin 4. Progesterone
Subtopic:  Vitamins, Hormones & Enzymes |
 53%
Level 3: 35%-60%
AIPMT - 2008
Hints

Which one of the following statements is not true?

1. In vulcanization, the formation of sulphur bridges between different chains makes rubber harder and stronger
2. The natural rubber has the trans-configuration at every double bond
3. Buna-S is a copolymer of butadiene and styrene
4. Buna-S is a copolymer of butadiene and styrene
Subtopic:  Polymers: Natural & Synthetic, Biodegradable & Non Biodegradable |
 85%
Level 1: 80%+
AIPMT - 2008
Hints

In the given hydrocarbon, 


The type/state of hybridization of carbons 1, 3, and 5 respectively are:

1. sp2, sp, sp3

2. sp, sp3, sp2

3. sp, sp2, sp3

4. sp3, sp2, sp

Subtopic:  Alkanes, Alkenes and Alkynes - Conformations and Hybridisation |
 91%
Level 1: 80%+
AIPMT - 2008
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The value of KP1 and Kp2 for the reactions
 X ⇋ Y +Z ......(i)
and A ⇋2B ......(ii) 
are in the ratio of 9 : 1. If the degree of dissociation of X and A is equal, then the total pressure at equilibrium(i) and (ii) are in the ratio:

1. 3 : 1

2. 1 : 9

3. 36 : 1

4. 1 : 1

Subtopic:  Kp, Kc & Factors Affecting them |
 63%
Level 2: 60%+
AIPMT - 2008
Hints

In DNA, the complementary bases are:

1. Adenine and thymine; guanine and cytosine

2. Adenine and thymine; guanine and uracil

3. Adenine and guanine, thymine and cytosine

4. Uracil and adenine; cytosine and guanine

Subtopic:   DNA, RNA & Metal Ions |
 93%
Level 1: 80%+
AIPMT - 2008
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The bromination of acetone occurring in an acid solution is represented by the equation. 
CH3COCH3(aq)+ Br2(aq) → 
CH3COCH2Br(aq) + H+(aq) + Br-(aq) 

The kinetic energy data were obtained for given reaction concentrations. 
Initial concentrations, M 
 CH3COCH3   Br2    H+

   0.30             0.05      0.05

   0.30             0.10      0.05

   0.30             0.10      0.10

   0.40             0.05      0.20
Initial rate, the disappearance of Br2, Ms-1 
5.7 × 10-5

5.7 ×  10-5

1.2 × 10-4

3.1 × 10-4
Based on the above data, the rate of the equation is:

1. Rate = k CH3COCH3 H+

2. Rate = k CH=COCH3 Br2

3. Rate = k CH3COCH3 Br2 H+2

4. Rate = k CH3COCH3 Br2 H+

Subtopic:  Definition, Rate Constant, Rate Law |
 67%
Level 2: 60%+
AIPMT - 2008
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Find the equilibrium constant for the reaction:

H₂(g) + I₂(g) ⇌ 2HI(g)

Given that:

HI(g) ⇌ ½H₂(g) + ½I₂(g)  K = 8

1. \(1 \over 16\) 2. \(1 \over 64\)
3. 16 4. \(1 \over 8\)
Subtopic:  Kp, Kc & Factors Affecting them |
 87%
Level 1: 80%+
AIPMT - 2008
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Links