The linear molecules among the following is:

1.  ${\mathrm{CH}}_3-\mathrm{C}\equiv \mathrm{C}-{\mathrm{CH}}_3$
2.  ${\mathrm{CH}}_2=\mathrm{CH}-{\mathrm{CH}}_2-\mathrm{C}\equiv \mathrm{CH}$
3.  ${\mathrm{CH}}_3-{\mathrm{CH}}_2-{\mathrm{CH}}_2-{\mathrm{CH}}_3$
4.  ${\mathrm{CH}}_3-\mathrm{CH}=\mathrm{CH}-{\mathrm{CH}}_3$

The Clemmensen reduction of a ketone is carried out in the presence of:

1. $\mathrm{Zn}$-$\mathrm{Hg}$ with $\mathrm{HCl}$

2. ${\mathrm{LiAlH}}_4$

3. ${\mathrm{H}}_2$ and $\mathrm{Pt}$ as a catalyst

4. Glycol with $\mathrm{KOH}$

If x is the amount of adsorbate and m is the amount of adsorbent, which of the following relations is not related to adsorption process?

1.  $\frac{\mathrm{x}}{\mathrm{m}}=\mathrm{f}\left(\mathrm{T}\right)$ $\mathrm{at}$ $\mathrm{constant}$ $\mathrm{P}$

2.  $\mathrm{p}=\mathrm{f}\left(\mathrm{T}\right)$ $\mathrm{at}$ $\mathrm{constant}$ $\left(\mathrm{x}/\mathrm{m}\right)$

3.  $\frac{\mathrm{x}}{\mathrm{m}}=\mathrm{p}\times \mathrm{T}$

4.  $\frac{\mathrm{x}}{\mathrm{m}}=\mathrm{f}\left(\mathrm{p}\right)$ $\mathrm{at}$ $\mathrm{constant}$ $\mathrm{T}$

The freezing point depression constant for water is 1.86 ^oC m^-1. If 5.00 g Na₂SO₄ is dissolved in 45.0 g H₂O, the freezing point is changed by -3.82 ^oC. The Van’t Hoff factor for Na₂SO₄ is:

Which of the two ions from the list given below have the geometry that is explained by the same hybridisation of orbitals, ${\mathrm{NO}}_2^{-},{\mathrm{NO}}_3^{-},{\mathrm{NH}}_2^{-},{\mathrm{NH}}_4^{-},{\mathrm{SCN}}^{-}$ ?

1.  ${\mathrm{NH}}_4^{-}$ $\mathrm{and}$ ${\mathrm{NO}}_3^{-}$

2.  ${\mathrm{SCN}}_{}^{-}$ $\mathrm{and}$ ${\mathrm{NH}}_2^{-}$

3.  ${\mathrm{NO}}_2^{-}$ $\mathrm{and}$ ${\mathrm{NH}}_2^{-}$

4.  ${\mathrm{NO}}_2^{-}$ $\mathrm{and}$ ${\mathrm{NO}}_3^{-}$

The d-electron configurations of Cr²⁺, Mn²⁺, Fe²⁺ and Co²⁺ are d⁴, d⁵, d⁶, and d⁷ respectively. Minimum paramagnetic behavior is shown by:
(At. No C = 24, Mn = 25, Fe = 26, Co = 27)

1. [Fe(H₂O)₆]²⁺

2. [Co(H₂O)₆]²⁺

3. [Cr(H₂O)₆]²⁺

4. [Mn(H₂O)₆]²⁺

1.  Fe>Mn>Co>Cr

2.  Co>Mn>Fe>Cr

3.  Cr>Mn>Co>Fe

4.  Mn>Fe>Cr>Co

The van’t Hoff factor, i, for a compound that undergoes
dissociation and association in a solvent is, respectively:

1. Less than one and less than one.
2. Greater than one and less than one.
3. Greater than one and greater than one.
4. Less than one and greater than one.