The correct splitting diagram of d orbitals in an octahedral crystal field is:
| 1. | ![]() |
2. | ![]() |
| 3. | ![]() |
4. | None of the above |
Optical isomerism is exhibited by among the following is/are:
| 1. | [Cr(Ox)3]3- | 2. | [PtCl2(en)2]2+ |
| 3. | [Cr(NH3)2Cl2en]+ | 4. | All of the above |
[Cr(NH3)6]3+ is paramagnetic ,while is diamagnetic because:
| 1. | Electrons in the 3d orbitals remain unpaired in |
| 2. | Electrons in the 3d orbitals remain unpaired in [Cr(NH3)6]3+ |
| 3. | Electrons in the 3p orbitals remain unpaired in [Cr(NH3)6]3+ |
| 4. | Electrons in the 3p orbitals remain unpaired in |
The crystal field splitting energy is:
| 1. | The heat of formation between the two levels (e and t2) in tetrahedral splitting |
| 2. | The total pairing energy of the two levels (e and t2) in tetrahedral splitting. |
| 3. | The sum of the energy levels in an octahedral crystal field splitting. |
| 4. | The combined energy of the two levels (eg and t2g) in octahedral splitting. |
A metal ion present in vitamin B12 is:
| 1. | Fe(II) | 2. | Co(III) |
| 3. | Zn(II) | 4. | Ca(II) |
The correct statement among the following regarding \(FeCO_5\) is:
1. Tetranuclear
2. Mononuclear
3. Trinuclear
4. Dinuclear
Number of geometrical isomer(s) possible for the complex [Cr(C2O4)3]3- is/are:
| 1. | 1 | 2. | 3 |
| 3. | 0 | 4. | 2 |
The correct statements about ethane-1,2-diamine as a ligand are:
| (a) | It is a neutral ligand |
| (b) | It is a bidentate ligand |
| (c) | It is a chelating ligand |
| (d) | It is a unidentate ligand |
| 1. | a and b | 2. | b and c |
| 3. | a, b and c | 4. | a, c and d |
The correct electronic configuration of the central atom in based on crystal field theory is:
| 1. | \(e^4 ~t_{2 g}^2 \) | 2. | \(t_{2 g}^4 ~e_g^2 \) |
| 3. | \(t_{2 g}^6 ~e_g^0 \) | 4. | \(e^3 ~t^3_{2g}\) |