Find the quantity that increases when the concentration of reactants in a reaction is increased.
| 1. | Heat of reaction | 2. | Threshold energy |
| 3. | Collision frequency | 4. | Activation energy |
Which of the following is the time required to reduce the amount of a reactant from 2.0 g to 0.2 g for a first-order reaction with rate constant \(k = 4.606 \times 10^{-3} \, \text{s}^{-1}\)?
| 1. | 200 s | 2. | 500 s |
| 3. | 1000 s | 4. | 100 s |
The half-life for a zero-order reaction having 0.02 M initial concentration of reactant is 100 s. The rate constant (in mol L–1 s–1) for the reaction is:
1.
2.
3.
4.
What does ZAB represent in the collision theory of chemical reactions?
| 1. | The fraction of molecules with energies greater than Ea |
| 2. | The collision frequency of reactants, A and B |
| 3. | Steric factor |
| 4. | The fraction of molecules with energies equal to Ea |
For a reaction, the activation energy is zero, and the rate constant at 200 K is 1.6 × 10⁶ s⁻¹.
Find the rate constant at 400 K.
Given: R = 8.314 J K⁻¹ mol⁻¹.
| 1. | 3.2 × 104 s-1 | 2. | 1.6 × 106s-1 |
| 3. | 1.6 × 103 s-1 | 4. | 3.2 × 106 s-1 |
A first-order reaction has a rate constant of 2.303 × 10¯3 s¯1. The time required for 40 g of this reactant to reduce to 10 g will be
[Given that ]
| 1. | 230.3 s | 2. | 301 s |
| 3. | 2000 s | 4. | 602 s |
For a reaction AB, enthalpy of reaction is and enthalpy of activation is . The correct potential energy profile for the reaction is:
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The slope of Arrhenius Plot (ln k v/s ) of the first-order reaction is . The value of Ea of the reaction is:
[Given R = 8.314 JK–1 mol–1]
| 1. | 166 kJ mol–1 | 2. | –83 kJ mol–1 |
| 3. | 41.5 kJ mol–1 | 4. | 83.0 kJ mol–1 |
For the chemical reaction ) the correct option is:
| 1. | \(3\frac {d[H_2]} {dt} = 2 \frac {d[NH_3]} {dt} \) | 2. | \(-\frac {1} {3}\frac {d[H_2]} {dt} = -\frac {1} {2} \frac {d[NH_3]} {dt} \) |
| 3. | \(- \frac{d \left[N_{2}\right]}{dt} = 2 \frac{d [NH_{3}]}{dt}\) | 4. | \(- \frac{d \left[N_{2}\right]}{dt} = \frac{1}{2} \frac{d [NH_{3}]}{dt}\) |
If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by:
1. t = 2.303/k
2. t = 0.693/k
3. t = 6.909/k
4. t = 4.606/k