Given below are certain reactions. Identify the reaction for which \(K_p \neq K_c .\)
1. \( \mathrm{H}_2(\mathrm{~g})+I_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{HI}(\mathrm{~g})\)
2. \( \mathrm{N}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{~g}) \)
3. \( \mathrm{N}_2(\mathrm{~g})+3 \mathrm{H}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_3(\mathrm{~g}) \)
4. \( \mathrm{H}_2 \mathrm{O}(\mathrm{~g})+\mathrm{CO}(\mathrm{~g}) \rightleftharpoons \mathrm{H}_2(\mathrm{~g})+\mathrm{CO}_2(\mathrm{~g}) \)
Subtopic:  Kp, Kc & Factors Affecting them |
 81%
Level 1: 80%+
NEET - 2026
Please attempt this question first.
Hints
Please attempt this question first.

For the reaction \(A(g) \rightleftharpoons 2B(g),\)  the backward reaction rate constant is higher than the forward reaction rate constant by a factor of \(2500\) at \(1000~K \).
\(K_p\) for the reaction at \(1000~ K\) is:
[ Given: \({R= 0.0831~ L ~\text{atm mol}^{-1} }K^{-1}]\)
1. \(0.033 \) 2. \(0.021 \)
3. \(83.1 \) 4. \(2 .077 \times 10^5\)
Subtopic:  Kp, Kc & Factors Affecting them |
 52%
Level 3: 35%-60%
NEET - 2025
Please attempt this question first.
Hints
Please attempt this question first.

For the reaction \(2 \mathrm{A} \rightleftharpoons \mathrm{B}+\mathrm{C}; ~\mathrm{K}_{\mathrm{c}}=4 \times 10^{-3}\).
At a given time, the composition of the reaction mixture is : \([\mathrm{A}]=[\mathrm{B}]=[\mathrm{C}]=2 \times 10^{-3} \mathrm{M} \text {. }\)

In light of the above facts, which of the following is correct?
1. Reaction has a tendency to go in the forward direction.
2. Reaction has a tendency to go in the backward direction.
3. Reaction has gone to completion in the forward direction.
4. Reaction is at an equilibrium.
Subtopic:  Kp, Kc & Factors Affecting them | Le Chatelier's principle |
 58%
Level 3: 35%-60%
NEET - 2024
Hints

advertisementadvertisement

In which of the following equilibria,\(\text{K}_\text{p}\) and \(\text{K}_\text{c}\) are NOT equal?
1. \(\mathrm{H}_{2(\mathrm{~g})}+\mathrm{I}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{HI}_{(\mathrm{g})}\)
2. \(\mathrm{CO}_{(\mathrm{g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})}\)
3. \(2 \mathrm{BrCl}_{(\mathrm{g})} \rightleftharpoons \mathrm{Br}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
4. \(\mathrm{PCl}_{5(\mathrm{~g})} \rightleftharpoons \mathrm{PCl}_{3(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})}\)
Subtopic:  Kp, Kc & Factors Affecting them |
 80%
Level 1: 80%+
NEET - 2024
Hints

Consider the given reaaction:
\(\mathrm{PCl}_5 \leftrightharpoons\mathrm{PCl}_3+\mathrm{Cl}_2\)
At equilibrium at \(500 \mathrm{~K},\) the concentration of \(\mathrm{PCl}_5=1.40~ \mathrm{M} \text {, }\) concentration of \(\mathrm{Cl}_2=1.60~ \mathrm{M} \text {, }\) concentration of \(\mathrm{PCl}_3=1.60 \mathrm{M}\). Calculate \(K_c\):

1. 2.00
2. 2.6
3. 1.83
4. 3.4
Subtopic:  Kp, Kc & Factors Affecting them |
 88%
Level 1: 80%+
NEET - 2024
Hints

For the equilibrium reaction:

2NOCl(g) ⇌ 2NO(g) + Cl₂(g)

The equilibrium constant in terms of concentration (Kc) is 3.0 × 10⁻⁶ at 1000 K.
Calculate the value of Kp for the reaction at this temperature.

 (Given R - 8.314 JK-1):
1. \(1.493\) 2. \(2.494\times10^{-2}\)
3. \(3.0\times10^{-6}\) 4. \(2.494\times10^{-4}\)
Subtopic:  Kp, Kc & Factors Affecting them |
 77%
Level 2: 60%+
NEET - 2024
Hints

advertisementadvertisement

Consider the following reaction taking place in 1L capacity container at 300 K.
\(\mathrm{A +B \rightleftharpoons C+D }\)
If one mole each of A and B are present initially and at equilibrium 0.7 mol of C is formed, then the equilibrium constant \((K_c) \) for the reaction is:

1. 9.7  2. 1.2 
3. 6.2  4. 5.4 
Subtopic:  Introduction To Equilibrium | Kp, Kc & Factors Affecting them |
 81%
Level 1: 80%+
NEET - 2022
Hints