Which of the following compounds is non-aromatic?

1. 2.
3. 4.

Subtopic:  Aromatic Hydrocarbons - Nomenclature, Isomerism & Huckel's Rule |
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Level 1: 80%+
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The treatment of \(\text {CH}_ 3 \text {MgX}\) with \(\text {CH}_ 3 \text {C ≡ CH}\) produces which of the following?

1. \(\text {CH}_ 3 \text C ≡ \text C \text {CH}_ 3\)

2. \(\text {CH}_ 3-\text {CH} = \text {CH}- \text {CH}_3\)

3. \(\text {CH}_ 4\)

4. \(\text {CH}_ 3 - \text {CH} = \text {CH}_ 2\)

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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Level 3: 35%-60%
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The hydrocarbon which can react with sodium in liquid ammonia is:

1. CH3CH2C≡CH

2. CH3CH=CHCH3

3. CH3CH2C≡CCH2CH3

4. CH3CH2CH2C≡CCH2CH2CH3

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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In the following sequence of reactions, the alkene CH₃CH=CHCH₃ undergoes ozonolysis followed by reductive workup (O₃, Zn/H₂O). The product formed is represented as ‘B’.

\(CH_3CH=CHCH_3 \xrightarrow {O_3} A \xrightarrow [Zn] { H_2O} B\),
Identify compound B.
 

1. CH3COCH3

2. CH3CH2COCH3

3. CH3CHO

4. CH3CH2CHO

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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Level 1: 80%+
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The electrophile, E⊕ attacks the benzene ring to generate the intermediate σ-complex. Of the following, which σ-complex is of the lowest energy?

1. 2.
3. 4.
Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
Level 3: 35%-60%
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Which of the following reactions will yield 2,2-dibromopropane?

1. CH3–C≡CH + 2HBr →

2. CH3CH=CHBr + HBr →

3. CH≡CH + 2HBr →

4. CH3–CH=CH2 + HBr →

Subtopic:  Alkanes, Alkenes and Alkynes - Chemical Properties |
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The reaction of toluene with Cl2 in the presence of FeCl3 gives predominantly:

1. Benzoyl chloride

2. Benzyl chloride

3. o-and p-Chlorotoluene

4. m-Chlorotoluene

Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions |
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The presence of a nitro group in a benzene ring:

1. Activates the ring towards electrophilic substitution
2. Renders the ring basic
3. Deactivates the ring towards nucleophilic substitution
4. Deactivates the ring towards electrophilic substitution
Subtopic:  Aromatic Hydrocarbons - Benzene - Structure, Preparation & Chemical Reactions | Aromatic Hydrocarbons - Reactions & Mechanism |
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Which one of the following conformations of cyclohexane is chiral?

1. Twist boat

2. Rigid

3. Chair

4. Boat

Subtopic:  Aliphatic Hydrocarbon -Nomenclature, Isomerism & Mechanism |
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 The compound among the following that shows geometrical isomerism is:

1. 1-Phenyl-2-butene

2. 3-Phenyl -1-butene

3. 2-Phenyl-1-butene

4. 1,1-Diphenyl-1-propene

Subtopic:  Alkanes, Alkenes and Alkynes - Conformations and Hybridisation |
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Level 1: 80%+
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