The half-life for a zero-order reaction having 0.02 M initial concentration of reactant is 100 s. The rate constant (in mol L–1 s–1) for the reaction is:

1. 1.0×10-4

2. 2.0×10-4

3. 2.0×10-3

4. 1.0×10-2

Subtopic:  Order, Molecularity and Mechanism |
 77%
Level 2: 60%+
NEET - 2020
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What does ZAB represent in the collision theory of chemical reactions?

1. The fraction of molecules with energies greater than Ea
2. The collision frequency of reactants, A and B
3. Steric factor
4. The fraction of molecules with energies equal to Ea
Subtopic:  Arrhenius Equation |
 73%
Level 2: 60%+
NEET - 2020
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For a reaction AB, enthalpy of reaction is -4.2 kJmol-1 and enthalpy of activation is 9.6 kJmol-1. The correct potential energy profile for the reaction is:

1. 2.
3. 4.
Subtopic:  Arrhenius Equation |
 75%
Level 2: 60%+
NEET - 2021
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The slope of Arrhenius Plot (ln k v/s 1T) of the first-order reaction is -5×103 K. The value of Ea of the reaction is:

[Given R = 8.314 JK–1 mol–1]

1. 166 kJ mol–1 2. –83 kJ mol–1
3. 41.5 kJ mol–1 4. 83.0 kJ mol–1
Subtopic:  Arrhenius Equation |
 79%
Level 2: 60%+
NEET - 2021
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Find the quantity that increases when the concentration of reactants in a reaction is increased.

1. Heat of reaction 2. Threshold energy
3. Collision frequency 4. Activation energy
Subtopic:  Arrhenius Equation |
 64%
Level 2: 60%+
NEET - 2020
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Which of the following is the time required to reduce the amount of a reactant from 2.0 g to 0.2 g for a first-order reaction with rate constant \(k = 4.606 \times 10^{-3} \, \text{s}^{-1}\)?

1. 200 s 2. 500 s
3. 1000 s 4. 100 s
Subtopic:  First Order Reaction Kinetics |
 84%
Level 1: 80%+
NEET - 2020
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The given graph is a representation of the kinetics of a reaction.

The y and x axes for zero and first-order reactions, respectively are:
1. zero order (y=rate and x=concentration), first order (y=rate and x=t1/2)
2. zero order (y=concentration and x=time), first order (y=t1/2 and x = concentration)
3. zero order (y=concentration and x= time), first order (y=rate constant and x= concentration)
4. zero order (y=rate and x=concentration), first order (y=t1/2 and x = concentration)
Subtopic:  Order, Molecularity and Mechanism |
 62%
Level 2: 60%+
NEET - 2022
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For a first-order reaction A \(\rightarrow\) Products, initial concentration of A is 0.1 M, which becomes 0.001 M after 5 minutes. Rate constant for the reaction in min-1 is

1. 0.2303 2. 1.3818 
3. 0.9212 4. 0.4606
Subtopic:  First Order Reaction Kinetics |
 72%
Level 2: 60%+
NEET - 2022
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For the reaction, 2A → B, rates= k[A]2. If the concentration of reactant is doubled, then the:

(a) rate of reaction will be doubled.
(b) rate constant will remain unchanged, however rate of reaction is directly proportional to the rate constant.
(c) rate constant will change since the rate of reaction and rate constant are directly proportional to each other.
(d) rate of reaction will increase by four times.

Identify the set of correct statements & choose the correct answer from the options given below:

1. (a) and (c) only 2. (a) and (b) only
3. (b) and (d) only 4. (c) and (d) only
Subtopic:  Definition, Rate Constant, Rate Law |
 69%
Level 2: 60%+
NEET - 2022
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The plot of ln k vs \({1 \over T}\) for the following reaction, \(2N_2O_5(g) \rightarrow 4NO_2 (g) + O_2(g) \) gives a straight line with the slope of the line equal to \(-1.0 \times 10^4 K \).
What is the activation energy for the reaction in J mol–1 ?
(Given: R = 8.3 J K1 mol1)

1. \(4.0 \times 10^2 \) 2. \(4.0 \times 10^{-2} \)
3. \(8.3 \times 10^{-4} \) 4. \(8.3 \times 10^4 \)
Subtopic:  Arrhenius Equation |
 79%
Level 2: 60%+
NEET - 2022
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