Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:

1. 1.85 × 10–5

2. 192 × 10–4

3. 178 × 10–5

4. 18.7 × 10–5

Subtopic:  Concentration Terms & Henry's Law |
 75%
Level 2: 60%+
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100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torr. If the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be:

1. 326 torr 2. 226 torr 
3. 360.7 torr 4. 280.7 torr
Subtopic:  Raoult's Law |
 55%
Level 3: 35%-60%
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The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is:

1. 1.02 g 2. 4.35 g
3. 2.87 g 4. 3.42 g
Subtopic:  Osmosis & Osmotic Pressure |
 65%
Level 2: 60%+
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If 22 g of benzene is dissolved in 122 g of CCl4, the mass percentage of CCl4 and benzene respectively are-

1. 15.28 %, 84.72% 

2. 84.72 %, 15.28 %

3. 8.72 %, 91.28%

4. 91.28 %, 8.72 %

Subtopic:  Concentration Terms & Henry's Law |
 69%
Level 2: 60%+
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Match the following type of intermolecular interactions present in the pair of compounds given:

(a) Methanol and Acetone (i) Van der Waal’s forces of attraction
(b) Acetonitrile and Acetone (ii) Ion-dipole interaction
(iii) Dipole-dipole interaction
 
(a) (b)
1. (iii) (ii)
2. (ii) (ii)
3. (iii) (iii)
4. (iii) (i)
Subtopic:  Azeotrope |
Level 3: 35%-60%
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What mass of urea is needed to prepare 2.5 kg of a 0.25 m aqueous solution?

1. 73 g 2. 37 g
3. 48 g 4. 24 g
Subtopic:  Concentration Terms & Henry's Law |
 81%
Level 1: 80%+
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The solubility of \(H_2S\) in water at STP is 0.195 m. The value of Henry's constant is:

1. 274 atm 2. 285 atm
3. 295 atm 4. 278 atm
Subtopic:  Concentration Terms & Henry's Law |
Level 3: 35%-60%
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The vapour pressure of water in the solution having 50 g of urea dissolved in 850 g of water is:

(Vapor pressure of pure water at 298 K is 23.8 mm Hg) 

1. 23.40 mm of Hg

2. 33.46 mm of Hg

3. 12.76 mm of Hg

4. 87.12 mm of Hg

Subtopic:  Relative Lowering of Vapour Pressure |
 74%
Level 2: 60%+
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The solubility of gases in liquids generally decreases as temperature increases.
The primary reason for this behavior is:

1. Dissolution of a gas in a liquid is an endothermic process. 
2. Dissolution of a gas in a liquid is an exothermic process. 
3. Gases are highly compressible.
4.

All of the above statements are correct.

Subtopic:  Introduction & Colligative properties |
 71%
Level 2: 60%+
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Which law is applied when deep-sea divers use a breathing mixture of oxygen and less soluble helium to minimise the painful effects caused by the increased dissolution of gases in blood at high pressure?

1. Raoult's law 2. Henry's law
3. Ideal gas Equation 4. All of the above
Subtopic:  Concentration Terms & Henry's Law |
 86%
Level 1: 80%+
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