Henry’s law constant for the solution of methane in benzene at 298 K is 4.27 × 105 mm Hg. The mole fraction of methane in benzene at 298 K under 760 mm Hg will be:

1. 1.85 × 10–5

2. 192 × 10–4

3. 178 × 10–5

4. 18.7 × 10–5

Subtopic:  Concentration Terms & Henry's Law |
 75%
Level 2: 60%+
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100 g of liquid A (molar mass 140 g mol–1) was dissolved in 1000 g of liquid B (molar mass 180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torr. If the total vapour pressure of the solution is 475 torr, the vapour pressure of pure liquid A will be:

1. 326 torr 2. 226 torr 
3. 360.7 torr 4. 280.7 torr
Subtopic:  Raoult's Law |
 55%
Level 3: 35%-60%
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Air consists primarily of nitrogen, which occupies approximately 79% by volume at 298 K under normal conditions. Water is in equilibrium with air at a total pressure of 10 atm and a temperature 298 K. The Henry's law constant for nitrogen in water at 298 K is given as 6.51 × 10⁷ mm Hg.

Determine the mole fraction of dissolved nitrogen in the water under these conditions:

1. 12.4 × 10−5

2. 9.22 × 10−5

3. 3.54 × 10

4. 4.96 × 
Subtopic:  Concentration Terms & Henry's Law |
 52%
Level 3: 35%-60%
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The amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27 °C is:

1. 1.02 g 2. 4.35 g
3. 2.87 g 4. 3.42 g
Subtopic:  Osmosis & Osmotic Pressure |
 65%
Level 2: 60%+
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Match the following type of intermolecular interactions present in the pair of compounds given:

(a) Methanol and Acetone (i) Van der Waal’s forces of attraction
(b) Acetonitrile and Acetone (ii) Ion-dipole interaction
(iii) Dipole-dipole interaction
 
(a) (b)
1. (iii) (ii)
2. (ii) (ii)
3. (iii) (iii)
4. (iii) (i)
Subtopic:  Azeotrope |
Level 3: 35%-60%
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The solubility of gases in liquids generally decreases as temperature increases.
The primary reason for this behavior is:

1. Dissolution of a gas in a liquid is an endothermic process. 
2. Dissolution of a gas in a liquid is an exothermic process. 
3. Gases are highly compressible.
4.

All of the above statements are correct.

Subtopic:  Introduction & Colligative properties |
 71%
Level 2: 60%+
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Which law is applied when deep-sea divers use a breathing mixture of oxygen and less soluble helium to minimise the painful effects caused by the increased dissolution of gases in blood at high pressure?

1. Raoult's law 2. Henry's law
3. Ideal gas Equation 4. All of the above
Subtopic:  Concentration Terms & Henry's Law |
 86%
Level 1: 80%+
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The correct match for the below table is:
Type of solution  Example
a. Solid in gas i. Aerated water
b. Gas in liquid  ii. Smoke
c. Liquid in solid iii. Solution of hydrogen in palladium 
d. Gas in solid iv. Amalgams
 
a b c d
1. i iii iv ii
2. ii i iv iii
3. iii i iv ii
4. iv i ii iii
Subtopic:  Introduction & Colligative properties |
 77%
Level 2: 60%+
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An example of a gas in a solid-type solution is:
1. Solution of hydrogen in palladium
2. Ethanol dissolved in water
3. Camphor vapours in N2 gas
4. Amalgams

Subtopic:  Introduction & Colligative properties |
 81%
Level 1: 80%+
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The incorrect formula among the following is:
1. \(\text X_{\text{mole fraction}}=\frac{\text n_{\text{solute}}}{\text n_{\text{solution}}}\)
2. \(\text{Molarity}=\frac{\text{amount of solute (g)}}{\text{volume of solution (mL)}}\)
3. \(\text{Molality}=\frac{\text{Number of mole of solute}}{\text{amount of solvent (kg)}}\)
4. \(\text{Mass percentage}=\frac{\text{mass of the component in the solution}}{\text{Total mass of the solution}}\times100 \)
Subtopic:  Concentration Terms & Henry's Law |
 84%
Level 1: 80%+
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