An enthalpy diagram for a particular reaction is given below:

Which of the following statements is correct?

1. Reaction is spontaneous
2. Reaction is non-spontaneous
3. The spontaneity of the reaction cannot be determined from the graph provided above.
4. None of the above

Subtopic:  Spontaneity & Entropy |
 54%
Level 3: 35%-60%
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What is the nature of the reaction depicted in the given diagram for A→C?

1. Exothermic 2. Endothermic
3. Reaction at equilibrium 4. None of these
Subtopic:  Enthalpy & Internal energy |
 83%
Level 1: 80%+
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Consider the following diagram for a reaction A→C. 


      

The nature of the reaction is-

1. Exothermic

2. Endothermic

3. Reaction at equilibrium

4. None of the above

Subtopic:  Enthalpy & Internal energy |
 85%
Level 1: 80%+
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Consider the following graph.

The work done, as per the graph above, is:

1. Positive 2. Negative
3. Zero 4. Cannot be determined
Subtopic:  First Law of Thermodynamics |
 73%
Level 2: 60%+
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For the graph given below, it can be concluded that work done during the process shown will be:

   

1. Zero 2. Negative
3. Positive 4. Cannot be determined
Subtopic:  First Law of Thermodynamics |
 69%
Level 2: 60%+
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What is the entropy change of the surroundings when 1.00 mol of liquid water (H₂O(l)) is formed under standard conditions?
[Given: ∆fHθ = –286 kJ mol–1 ]

1. 952. 5 J mol-1

2. 979.7 J mol-1

3. 949.7 J mol-1

4. 959.7 J mol-1

Subtopic:  Spontaneity & Entropy |
 55%
Level 3: 35%-60%
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Find the thermodynamic stability of NO(g) relative to NO₂(g) using the following data:

½N₂(g) + ½O₂(g) → NO(g)  ΔrH° = +90 kJ mol⁻¹

NO(g) + ½O₂(g) → NO₂(g)  ΔrH° = −74 kJ mol⁻¹
1. Less than NO₂(g)
2. More than NO₂(g)
3. Equal to NO₂(g)
4. Insufficient data

Subtopic:  Enthalpy & Internal energy |
 71%
Level 2: 60%+
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The difference between enthalpy (∆H) and internal energy (∆E) for the given below reaction,
under constant temperature, is:
\(C_{3} H_{8} \left(\right. g \left.\right) + 5 O_{2} \left(\right. g \left.\right) \rightarrow 3 CO_{2} \left(\right. g \left.\right) + 4 H_{2} O \left(\right. l \left.\right)\)

1. + RT 2. – 3RT
3. + 3RT 4. – RT
Subtopic:  Enthalpy & Internal energy |
 85%
Level 1: 80%+
AIPMT - 2003
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For the given reaction 

2H2O2(l) → 2H2O(l) + O2(g), the heat of formations of H2O2(l)  and H2O (l) are -188 kJ/mol & -286 KJ/mol respectively. The change in the enthalpy of the reaction will be:

1.  – 196 kJ/mol

2.  + 196 kJ/mol

3.  + 948 kJ/mol

4.  – 948 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 77%
Level 2: 60%+
AIPMT - 2001
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Select the correct option based on statements below:
Assertion (A): Work done in an irreversible isothermal process at constant volume is zero.
Reason (R):  Work is assigned a negative sign during expansion and is assigned a positive sign during compression.
 
1. Both (A) and (R) are true and (R) is the correct explanation of (A).
2. Both (A) and (R) are true but (R) is not the correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

Subtopic:  First Law of Thermodynamics |
 79%
Level 2: 60%+
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