The most stable carbocation among the following is:

1. 2.
3. 4.

Subtopic:  Reaction Intermediates ; Preparation & Properties |
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The increasing order of stability of the following free radicals is:

1. \(\small{({CH}_3})_2 \dot{{C}}H<{({CH}_3})_3 \dot{{C}}<{({C}_6 {H}_5})_2 \dot{{C}}H <{({C}_6 {H}_5})_3 \dot{{C}}\)
2. \(\small({{C}_{6} {H}_{5})}_{3} \dot{{C}}<({{C}_{6} {H}_{5})}_{2} \dot{{C}} {H}<({{CH}_{3})}_{3} \dot{{C}}<({{CH}_{3})}_{2} \dot{{C}}H\)
3. \(\small({{C}_{6} {H}_{5})}_{2} \dot{{C}} {H}<({{C}_{6} {H}_{5})}_{3} \dot{{C}}<({{CH}_{3})}_{3} \dot{{C}} <({{CH}_{3})}_{2} \dot{{C}}H \)
4. \(\small({{CH}_{3})}_{2} \dot{{C}} {H}<({{CH}_{3})}_{3} \dot{{C}}<({{C}_{6} {H}_{5})}_{3} \dot{{C}} <({{C}_{6} {H}_{5})}_{2} \dot{{CH}}\)
Subtopic:  Electron Displacement Effects |
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The compound formed in the positive test for nitrogen with the Lassaigne solution of an organic compound is:

1. Fe4[Fe(CN)6]3

2. Na3[Fe(CN)6]

3. Fe(CN)3

4. Na4[Fe(CN)5NOS]

Subtopic:  Qualitative Analysis of Organic Compounds |
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The correct structural formula of 5-nitro-3-methoxy-3-methylhexanoyl chloride among the following is:

1. 
2.
3.  
4.   
Subtopic:  Structural Isomers |
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The sodium extract of an organic compound on acidification with acetic acid and the addition of lead acetate solution gives a black precipitate.

The organic compound contains:

1. Nitrogen 2. Halogen
3. Sulphur 4. Phosphorus
Subtopic:  Qualitative Analysis of Organic Compounds |
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What is the IUPAC name of the given compound?
 

1. 1, 1-Diethyl-2-dimethylpentane

2. 4, 4-Dimethyl-5, 5-diethylpentane

3. 5, 5-Diethyl-4, 4-dimethylpentane

4. 3-Ethyl-4, 4-dimethylheptane

Subtopic:  Nomenclature |
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The IUPAC name of neopentane is :

1. 2-Methylbutane

2. 2, 2-Dimethylpropane

3. 2-Methylpropane

4. 2, 2-Dimethylbutane

Subtopic:  Nomenclature |
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The distillation technique most suited for separating glycerol from spent-lye in the soap industry is :

1. Steam distillation
2. Distillation under reduced pressure
3. Fractional distillation
4. Differential extraction

Subtopic:  Purification of Organic Compounds |
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In an estimation of bromine by the Carius method, 1.6 g of an organic compound gave 1.88 g of AgBr. The mass percentage of bromine in the compound is: 

[Atomic mass, Ag=108, Br = 80 g mol-1]

1. 50 %
2. 55.5%
3. 60 %
4. 70 %

Subtopic:  Quantitative Analysis of Organic Compounds |
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The correct order of stability of following carbocation is-

1. b > a > c 2. a > c > b
3. a > b > c 4. c > b > a
Subtopic:  Electron Displacement Effects | Reaction Intermediates ; Preparation & Properties |
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