The respective oxidation states of P in H4P2O5, H4P2O6, and H4P2O7 are:
| 1. | +3, +5, and +4 | 2. | +5, +3, and +4 |
| 3. | +5, +4, and +3 | 4. | +3, +4, and +5 |
A solid (A) reacts with strong aqueous NaOH, liberating a foul smelling gas (B), which spontaneously burns in the air, giving smoky rings. A and B are, respectively:
1. P4 (red) and PH3
2. P4 (white) and PH3
3. S8 and H2S
4. P4 (white) and H2S
Which of the following orders is incorrect for the given properties of halogens?
| 1. | F2 > Cl2 > Br2 > I2 | Oxidising power |
| 2. | F < Cl > Br > I | Electron gain enthalpy |
| 3. | F2 > Cl2 > Br2 > I2 | Bond dissociation energy |
| 4. | F> Cl > Br > I | Electronegativity |
Which of the following represents the number of S=O bonds present in H₂S₂O₈?
| 1. | 1 | 2. | 2 |
| 3. | 3 | 4. | 4 |
Which of the following equations correctly represents the catalytic oxidation of ammonia by atmospheric oxygen ?
| 1. | 4NH3 + \(\underset{\text{From air}}{5O_2} \) \(\xrightarrow[\text{500 K; 9 bar}]{\text{Pt / Rh gauge catalyst}}\) 4NO + 6H2O |
| 2. | 3NH4 + \(\underset{\text{From air}}{5O_2} \) \(\xrightarrow[\text{500 K; 9 bar}]{\text{Pt / Rh gauge catalyst}}\) 3NO + 6H2O |
| 3. | 4NH3 + \(\underset{\text{From air}}{5O_2} \) \(\xrightarrow[\text{cold}]{\text{no catalyst}}\) 4NO + 6H2O |
| 4. | 3NH4 + \(\underset{\text{From air}}{5O_2} \) \(\xrightarrow[\text{cold}]{\text{no catalyst}}\) 3NO + 6H2O |
Which of the following structures correctly represents pyrophosphoric acid,?
| 1. | ![]() |
2. | ![]() |
| 3. | ![]() |
4. | ![]() |
Which of the following correctly explains why NH₃ is highly soluble in water, whereas PH₃ is only sparingly soluble?
| 1. | NH3 forms an H-bond with water, so it is soluble but PH3 does not form an H-bond. |
| 2. | NH3 does not form an H-bond with water, so it is soluble but PH3 does form an H-bond. |
| 3. | NH3 and PH3 both form H-bond with water. |
| 4. | NH3 and PH3 both do not form H-bond with water. |
The disproportionation reaction of is as follows:
X and Y in the above reaction are:
1. H3PO2, HPO2
2. H3PO4, PH3
3. H2PO6, PO3
4. None of the above.
Which of the following represents the correct increasing order of basic strength of the Group 15 hydrides?
1. BiH3 \(\simeq \) SbH3 < AsH3 < PH3 < NH3
2. BiH3 > NH3 > PH3 > SbH3 > AsH3
3. SbH3 < AsH3 < PH3 < NH3 < BiH3
4. AsH3 > NH3 > PH3 > SbH3 > BiH3
Which of the following hydrides has the lowest pKa value?
1. H2O
2. H2S
3. H2Se
4. H2Te