The formation of the oxide ion, O²⁻(g), from an oxygen atom occurs in two successive steps:

O(g) + e⁻ → O⁻(g)  ΔH = −141 kJ mol⁻¹

O⁻(g) + e⁻ → O²⁻(g)  ΔH = +780 kJ mol⁻¹

Although O²⁻ is isoelectronic with neon, its formation in the gaseous state is energetically unfavourable. What is the main reason for this?

1. Electron repulsion outweighs the stability gained by achieving a noble gas configuration.
2. O ion has a comparatively smaller size than the oxygen atom.
3. Oxygen is more electronegative.
4. Addition of electrons in oxygen results in a large size of the ion.
Subtopic:  Electron Affinity (EA) |
 76%
Level 2: 60%+
NEET - 2015
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The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii increase?
1.  Ar < K< Ca2+
2. Ca2+ < Ar < K+
3. Ca2+ < K< Ar
4. K+ < Ar < Ca2+

Subtopic:  Atomic Size |
 84%
Level 1: 80%+
NEET - 2015
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Which of the following represents the correct order of ionic radii?

1. H⁻ > H⁺ > H
2. Na⁺ > F⁻ > O²⁻
3. F⁻ > O²⁻ > Na⁺
4. N³⁻ > Mg²⁺ > Al³⁺
Subtopic:  Atomic Size |
 82%
Level 1: 80%+
AIPMT - 2014
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Which of the following ionic species is isoelectronic with \(\mathrm{Be^{2+}}\)?

1. H+ 2. Li+
3. Na+ 4. Mg2+
Subtopic:  Electronic Configuration |
 92%
Level 1: 80%+
AIPMT - 2014
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What is the correct order of electron gain enthalpy from least negative to most negative for the elements C, Ca, Al, F, and O?
1. Al < Ca < O < C < F
2. Al < O < C < Ca < F
3. C < F < O < Al < Ca
4. Ca < Al < C < O < F
Subtopic:  Electron Affinity (EA) |
 82%
Level 1: 80%+
NEET - 2013
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The first ionization enthalpy of sodium (Na) is 5.1eV. Using this information, determine the value of the electron gain enthalpy of \(\mathrm{Na^+}\):

1. +10.2 eV 

2. –5.1 eV

3. –10.2 eV 

4. +2.55 eV

Subtopic:  Electron Affinity (EA) |
 81%
Level 1: 80%+
AIPMT - 2011
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The correct order of the decreasing ionic radii among the following isoelectronic species is:

1. Ca2+>K+>S2->Cl-

2. Cl->S2->Ca2+>K+

3. S2->Cl->K+>Ca2+

4. K+>Ca2+>Cl->S2-

Subtopic:  Atomic Size |
 88%
Level 1: 80%+
AIPMT - 2010
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The correct order of increasing electron affinity for the elements, O, S, F and Cl is:

1. Cl < F < O < S 2. O < S < F < Cl
3. F < S < O < Cl 4. S < O < Cl < F
Subtopic:  Electron Affinity (EA) |
 79%
Level 2: 60%+
AIPMT - 2010
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Among the elements Ca, Mg, P and Cl, the correct order of increasing atomic radii is:
1. Cl < P < Mg < Ca
2. P < Cl < Ca < Mg
3. Ca < Mg < P < Cl
4. Mg < Ca < Cl < P

Subtopic:  Atomic Size |
 80%
Level 1: 80%+
AIPMT - 2010
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Amongst the elements with the following electronic configurations, which one of them may have the highest ionisation energy?

1. [Ne] 3s2 3p2

2. [Ne] 3s2 3p3

3. [Ar] 3d10 4s2 4p3

4. [Ne] 3s2 3p1

Subtopic:  Ionization Energy (IE) | Electronic Configuration |
Level 4: Below 35%
AIPMT - 2009
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