The formation of the oxide ion, O²⁻(g), from an oxygen atom occurs in two successive steps:
O(g) + e⁻ → O⁻(g) ΔH = −141 kJ mol⁻¹
O⁻(g) + e⁻ → O²⁻(g) ΔH = +780 kJ mol⁻¹
Although O²⁻ is isoelectronic with neon, its formation in the gaseous state is energetically unfavourable. What is the main reason for this?
| 1. | Electron repulsion outweighs the stability gained by achieving a noble gas configuration. |
| 2. | O– ion has a comparatively smaller size than the oxygen atom. |
| 3. | Oxygen is more electronegative. |
| 4. | Addition of electrons in oxygen results in a large size of the ion. |
The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii increase?
1. Ar < K+ < Ca2+
2. Ca2+ < Ar < K+
3. Ca2+ < K+ < Ar
4. K+ < Ar < Ca2+
Which of the following represents the correct order of ionic radii?
1. H⁻ > H⁺ > HWhich of the following ionic species is isoelectronic with \(\mathrm{Be^{2+}}\)?
| 1. | 2. | ||
| 3. | 4. |
The first ionization enthalpy of sodium (Na) is 5.1eV. Using this information, determine the value of the electron gain enthalpy of \(\mathrm{Na^+}\):
1. +10.2 eV
2. –5.1 eV
3. –10.2 eV
4. +2.55 eV
The correct order of the decreasing ionic radii among the following isoelectronic species is:
1.
2.
3.
4.
The correct order of increasing electron affinity for the elements, O, S, F and Cl is:
| 1. | Cl < F < O < S | 2. | O < S < F < Cl |
| 3. | F < S < O < Cl | 4. | S < O < Cl < F |
Among the elements Ca, Mg, P and Cl, the correct order of increasing atomic radii is:
1. Cl < P < Mg < Ca
2. P < Cl < Ca < Mg
3. Ca < Mg < P < Cl
4. Mg < Ca < Cl < P
Amongst the elements with the following electronic configurations, which one of them may have the highest ionisation energy?
1.
2.
3.
4.