Match List-I (Equations) with List-II (Type of processes) and select the correct option.
| List-I (Equation) |
List-II (Type of processes) |
||
| (a) | Kp > Q | (i) | Non-spontaneous |
| (b) | ∆Gº < RT ln Q | (ii) | Equilibrium |
| (c) | Kp = Q | (iii) | Spontaneous and endothermic |
| (d) | T > \(\frac{\Delta H}{\Delta S}\) | (iv) | Spontaneous |
| Options: | (a) | (b) | (c) | (d) |
| 1. | (iii) | (iv) | (ii) | (i) |
| 2. | (iv) | (i) | (ii) | (iii) |
| 3. | (ii) | (i) | (iv) | (iii) |
| 4. | (i) | (ii) | (iii) | (iv) |
A reaction occurs spontaneously if:
1. T∆S > ∆H and ∆H is +ve and ∆S are –ve
2. T∆S = ∆H and both ∆H and ∆S are +ve
3. T∆S < ∆H and both ∆H and ∆S are +ve
4. T∆S > ∆H and both ∆H and ∆S are +ve
Which of the following pairs of chemical reactions is certain to result in a spontaneous reaction:
1. Endothermic and decreasing disorder
2. Exothermic and increasing disorder
3. Endothermic and increasing disorder
4. Exothermic and decreasing disorder
Find the correct entropy condition for a spontaneous process.
1. ΔSsurroundings > 0 onlyWhat is the entropy change (in JK–1 mol–1) when one mole of ice is converted into water at 0 ºC?
(The enthalpy change for the conversion of ice to liquid water is 6.0 KJ mol–1 at 0 ºC)
| 1. | 20.13 | 2. | 2.013 |
| 3. | 2.198 | 4. | 21.98 |
The unit of entropy is:
| 1. | JK–1 mol–1 | 2. | J mol–1 |
| 3. | J–1K–1 mol–1 | 4. | JK mol–1 |
2 mole of an ideal gas at 27ºC temp. is expanded reversibly from 2 lit. to 20 lit. Find entropy change (R = 2 cal/mol K):
| 1. | 92.1 | 2. | 0 |
| 3. | 4 | 4. | 9.2 |
At 27°C, the latent heat of fusion of a substance is 2930 J mol⁻¹.
Calculate the entropy change (ΔS) for the process:
1. 9.77 J/mol K
2. 10.77 J/mol K
3. 9.07 J/mol K
4. 0.977 J/mol K