The standard enthalpy of vaporization ∆vapHo for water at 100 oC is 40.66 kJ mol–1. The internal energy of vaporization of water at 100 oC (in kJ mol–1) is: 
(Assume water vapour behaves like an ideal gas.)

1. +37.56 2. –43.76
3. +43.76 4. +40.66
Subtopic:  Enthalpy & Internal energy |
 61%
Level 2: 60%+
AIPMT - 2012
Hints

Calculate the H–H bond dissociation energy from the following reaction:

4H(g) → 2H₂(g)  ΔH = −869.6 kJ

1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 67%
Level 2: 60%+
AIPMT - 2011
Hints

Consider the following processes:

                                       ∆H (kJ/mol)
½ A → B                            + 150
3B → 2C + D                      –125
E + A → 2D                        +350

For B + D → E + 2C, ∆H will be:

1. 325 kJ/mol 

2. 525 kJ/mol

3. –175 kJ.mol 

4. –325 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 76%
Level 2: 60%+
AIPMT - 2011
Hints

advertisementadvertisement

The following two reactions are knownFe2O3(s)+3CO(g)→2Fe(s)+3CO2(g);
∆H=-26.88 kJ
FeO(s)+CO(g)→Fe(s)+CO2(g);
∆H=-16.5 kJ

The value of ∆H for the following reaction

Fe2O3(s)+CO(g)→2FeO(s)+CO2(g) is:

1. -43.3 kJ

2. -10.3 kJ

3. +6.2 kJ

4. +10.3 kJ

Subtopic:  Enthalpy & Internal energy |
 78%
Level 2: 60%+
AIPMT - 2010
Hints

The difference between enthalpy (∆H) and internal energy (∆E) for the given below reaction,
under constant temperature, is:
\(C_{3} H_{8} \left(\right. g \left.\right) + 5 O_{2} \left(\right. g \left.\right) \rightarrow 3 CO_{2} \left(\right. g \left.\right) + 4 H_{2} O \left(\right. l \left.\right)\)

1. + RT 2. – 3RT
3. + 3RT 4. – RT
Subtopic:  Enthalpy & Internal energy |
 85%
Level 1: 80%+
AIPMT - 2003
Hints
Links

For the given reaction 

2H2O2(l) → 2H2O(l) + O2(g), the heat of formations of H2O2(l)  and H2O (l) are -188 kJ/mol & -286 KJ/mol respectively. The change in the enthalpy of the reaction will be:

1.  – 196 kJ/mol

2.  + 196 kJ/mol

3.  + 948 kJ/mol

4.  – 948 kJ/mol

Subtopic:  Enthalpy & Internal energy |
 77%
Level 2: 60%+
AIPMT - 2001
Hints
Links

advertisementadvertisement

The enthalpy of \(CH_4 + \dfrac{1}{2 }O_2 \rightarrow\ CH_3OH\) is negative. If enthalpy of combustion of methane and \(CH_3OH\) are x and y, respectively, then which of the following relations is correct?

1. x > y 2. x < y
3. x = y 4. x ≥ y
Subtopic:  Enthalpy & Internal energy |
 63%
Level 2: 60%+
AIPMT - 2001
Hints

For the reaction, 
C2H5OH(l) + 3O2(g) →2CO2(g) + 3H2O(l)
which one is true?

1. ∆H = ∆E – RT 2. ∆H = ∆E + RT
3. ∆H = ∆E + 2RT 4. ∆H = ∆E – 2RT
Subtopic:  Enthalpy & Internal energy |
 85%
Level 1: 80%+
AIPMT - 2000
Hints

Which of the following statements are true for a cyclic process?

a. W = 0 b. ∆E = 0
c. ∆H = 0 d. ∆E ≠ 0

1.  a, b
2.  b, c
3.  c, d
4.  a, d

Subtopic:  Enthalpy & Internal energy |
 72%
Level 2: 60%+
AIPMT - 1999
Hints

advertisementadvertisement

If a system is expanded under adiabatic process, then:
1. Temperature increases
2. ∆E decreases
3. ∆E increases
4. None of the above

Subtopic:  Enthalpy & Internal energy |
 65%
Level 2: 60%+
AIPMT - 1999
Hints