| 1. | \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) | 2. | \(\Delta_{\mathrm{r}} \mathrm{H}<0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0 \) |
| 3. | \(\Delta_{\mathrm{r}} \mathrm{H}<0 \) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) | 4. | \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0\) |