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| List-I (Reactions) |
List-II (Products) |
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I. | \(\small\mathrm{{\left({CH}_3\right)_2 {C}={O}+{CO}_2+\mathrm{H}_2 {O} }}\) |
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III. | ![]() |
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IV. | \(\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{OH} \) |
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Determine the IUPAC name of the compound with the molecular formula C₆H₁₄ that contains two tertiary carbon atoms.
1. 2-Methyl pentane
2. 2, 3-Dimethylbutane
3. 2, 2-Dimethylbutane
4. n-Hexane
| Statement I: | The boiling point of three isomeric pentanes follows the order, \(\small\text { n-Pentane }>\text { Isopentane }>\text { Neopentane }\) |
| Statement II: | When branching increases, the molecule attains the shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. |
| 1. | \((CH_3)_3C(CH_2)_2CH_3~~~~~~~~~~~~~\) |
| 2. | 4-isobutyl heptane |
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| 4. |
| 1. | 33% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 2. | 50% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
| 3. | 100% p character and are at a lower energy level than the electron pair in the \(\sigma -\) bond. |
| 4. | 100% p character and are at a higher energy level than the electron pair in the \(\sigma -\) bond. |
The dihedral angle of the least stable conformer of ethane is:
| 1. | 60° | 2. | 0° |
| 3. | 120° | 4. | 180° |
An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one.
The IUPAC name of ‘A’ is :
1. 3-Ethylpent-2-ene
2. 3-Ethylpent-2- yne
3. 2-Ethylpent-3-ene
4. 3-Ethylpent-4-yne
A compound possessing optical isomerism provided it has the molecular formula C7H16, would be:
| 1. | 2,3-Dimethyl pentane | 2. | 2,2-Dimethyl butane |
| 3. | 2-Methyl hexane | 4. | None of the above |