What is the effect of heating H₃BO₃ at 370 K and above?
1. Orthoboric acid changes to metaboric acid.
2. Metaboric acid changes to boric oxide.
3. Both '1' and '2'
4. Neither '1' nor '2'
Which of the following compounds is electron-deficient?
1.
2.
3.
4.
The hybridization of carbon in (a) (b) diamond (c) graphite is respectively:
1. , ,
2. , ,
3. , ,
4. , ,
Why is the B–F bond length in BF₃ (130 pm) shorter than that in BF₄⁻ (143 pm)?
1. Presence of triple-bond character in
2. Resonance in
3. Presence of a double-bond character in
4. Presence of a double bond character in
Despite the dipole moment in the B–Cl bond, the BCl3 molecule as a whole has no dipole moment because:
| 1. | The respective dipole-moments of the B–Cl bond add with each other |
| 2. | The respective dipole moments of the B–Cl bond cancel each other |
| 3. | BCl3 is tetrahedral in shape |
| 4. | None of the above |
Why carbon monoxide (CO) is poisonous?
| 1. | It forms a complex with hemoglobin. |
| 2. | The CO–Hb complex is about 300 times more stable than the O 2 –Hb complex. |
| 3. | It can kill a person through suffocation on not receiving oxygen. |
| 4. | All of the above. |
An excessive content of CO2 is responsible for global warming as:
| 1. | Higher the level of carbon dioxide, higher is the amount of heat trapped. |
| 2. | Higher the level of oxygen, higher is the amount of heat trapped. |
| 3. | Higher the level of carbon dioxide, lesser is the amount of heat trapped. |
| 4. | Higher the level of oxygen, lesser is the amount of heat trapped. |
The first ionization enthalpy decreases sharply from carbon to silicon in Group 14. What is the main reason for this decrease?
| 1. | Decrease in the charge of elements upon moving down the group. |
| 2. | Decrease in the atomic sizes of elements upon moving down the group. |
| 3. | Increase in the atomic sizes of elements upon moving down the group. |
| 4. | Increase in the charge of elements upon moving down the group. |
Which of the following best explains why the atomic radius of gallium is smaller than that of aluminium?
1. Poor shielding effect of the 2d-electrons
2. Poor shielding effect of the 3d-electrons
3. Poor shielding effect of the 3p-electrons
4. Poor shielding effect of the 2s-electrons
Identify the pair in which both oxides are amphoteric in nature.
1. Tl2O3, SiO2
2. ,
3. ,
4. Al2O3 , PbO2