Q. No.Identify the correct formula of 'oleum' from the following
1.
H2S2O7
2.
H2SO3
3.
H2SO4
4.
H2S2O8
Which of the following oxoacids of phosphorus shows the strongest reducing property?
1. H4P2O72. H3PO3
3. H3PO2
4. H3PO4
A compound "X", upon reaction with H2O, produces a colourless gas "Y" with a rotten fish smell. Gas 'Y' is absorbed in a solution of CuSO4 to give Cu3P2 as one of the products. The compound 'X' will be:
1. Ca3P2
2.
3.
4. Ca3(PO4)2
False statement regarding PCl5 is:
| 1. | PCl5 molecule is non-reactive. |
| 2. | Three equatorial P-Cl bonds make an angle of 120° with each other. |
| 3. | Two axial P-Cl bonds make an angle of 180° with each other. |
| 4. | Axial P-Cl bonds are longer than equatorial P-Cl bonds. |
Match the name of process given in Column-I with the name of compound given in Column-II and mark the correct option.
| Column-I | Column-II | ||
| (a) | Pure nitrogen | (i) | Chlorine |
| (b) | Haber process | (ii) | Sulphuric acid |
| (c) | Contact process | (iii) | Ammonia |
| (d) | Deacon's process | (iv) | Sodium azide or Barium azide |
| (a) | (b) | (c) | (d) | |
| 1. | (iv) | (iii) | (ii) | (i) |
| 2. | (i) | (ii) | (iii) | (iv) |
| 3. | (ii) | (iv) | (i) | (iii) |
| 4. | (iii) | (iv) | (ii) | (i) |
Match the Xenon compounds in Column-I with their structure in Column-II and assign the correct code:
| Column-I | Column-II | ||
| (a) | XeF4 | (i) | Pyramidal |
| (b) | XeF6 | (ii) | Square planar |
| (c) | XeOF4 | (iii) | Distorted octahedral |
| (d) | XeO3 | (iv) | Square pyramidal |
Code:
| (a) | (b) | (c) | (d) | |
| 1. | (iii) | (iv) | (i) | (ii) |
| 2. | (i) | (ii) | (iii) | (iv) |
| 3. | (ii) | (iii) | (iv) | (i) |
| 4. | (ii) | (iii) | (i) | (iv) |
The correct thermal stability order for \(\mathrm{{H}_2 {E}},\) \(\mathrm{{ E}= {O}, {S}, {Se}, {Te}} \text { and } \mathrm{Po}\) among the following is:
1. \(\mathrm{{H}_2 {Se}<{H}_2 {Te}<{H}_2 {Po}<{H}_2 {O}<{H}_2 S}\)
2. \(\mathrm{{H}_2 {~S}<{H}_2 {O}<{H}_2 {Se}<{H}_2 {Te}<{H}_2 {Po}}\)
3. \(\mathrm{{H}_2 {O}<{H}_2 {~S}<{H}_2 {Se}<{H}_2 {Te}<{H}_2 {PO}}\)
4. \(\mathrm{{H}_2 {Po}<{H}_2 {Te}<{H}_2 {Se}<{H}_2 {~S}<{H}_2 {O}}\)
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:
| 1. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction |
| 2. | In NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions |
| 3. | In NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions |
| 4. | In NH3 the atomic dipole and the bond dipole is in opposite directions whereas in NF3 these are in the same directions |
Which of the following represents the oxidation states of phosphorus in H4P2O5, H4P2O6, H4P2O7, respectively?
| 1. | +3, +5, +4 | 2. | +5, +3, +4 |
| 3. | +5, +4, +3 | 4. | +3, +4, +5 |
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