Consider the following ionisation reactions :

I.E. (kJ mol-1)

AgAg++e-,A1
B(g)+B(g)2++e-,B2
C(g)+C(g)2++e-,C2
B(g)B(g)++e-,B1
C(g)C(g)++e-,C1
C(g)2+C(g)3++e-,C3

If monovalent positive ion of A, divalent positive ion of B and trivalent positive ion of C have zero electron. Then incorrect order of corresponding I.E. is :

(1) C3>C2>B2                       

(2) B1>A1>C1

(3) C3>C2>B2                       

(4) B2>C3>A1

Subtopic:  Ionization Energy (IE) |
Level 3: 35%-60%
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Find the incorrect match among the following electronic configurations and their corresponding period and group numbers.

1. [Ar] 3d⁵ 4s¹ → 4th period, 6th group
2. [Kr] 4d¹⁰ → 5th period, 12th group
3. [Rn] 6d² 7s² → 7th period, 3rd group
4. [Xe] 4f¹⁴ 5d² 6s² → 6th period, 4th group

Subtopic:  Electronic Configuration |
 51%
Level 3: 35%-60%
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 Which of the following orders is correct for the property mentioned in brackets?
 1.S²⁻ > Cl⁻ > K⁺ > Ca²⁺ (Ionisation energy)
 2. C < N < F < O (Second ionisation energy)
 3. B > Al > Ga > In > Tl (Electronegativity)
 4. Na⁺ > Li⁺ > Mg²⁺ > Be²⁺ > Al³⁺ (Ionic radius)

Subtopic:  Ionization Energy (IE) |
 51%
Level 3: 35%-60%
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IP1 and IP2 for Mg are 178 Kcal mol–1 and 348 Kcal mol-1, respectively. The energy required for the reaction, MgMg2+ + 2e- will be:

1. +170 Kcal mol-1

2. +526 Kcal mol-1

3. –170 Kcal mol-1

4. –526 Kcal mol-1

Subtopic:  Ionization Energy (IE) |
 77%
Level 2: 60%+
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Incorrect statement about characteristics regarding halogens is :

1. Ionization energy decreases with increase in atomic number.

2. Electronegativity decreases with increase in atomic number.

3. Electron affinity decreases with increase in atomic number.

4. Enthalpy of fusion increases with increase in atomic number. 

Subtopic:  Electron Affinity (EA) |
 51%
Level 3: 35%-60%
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The process requiring the absorption of energy is :

1. FF-

2. HH-

3. ClCl-

4. OO2-

Subtopic:  Electron Affinity (EA) |
 70%
Level 2: 60%+
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Consider the following statements:

(I) Rutherford name was associated with the development of periodic table.
(II) A metal M having electronic configuration  \(1 s^2, 2 s^2, 2 p^6, 3 s^2, 3 p^6, 3 d^{10}, 4 s^1\)  is d-block element.
(III) Diamond is an element.
(IV)

The electronic configuration of the most electronegative elements is\(1 s^2, 2 s^2, 2 p^5\)

Choose the correct option from the given codes.

1. I, II, IV 2. I, II, III, IV
3. II, IV 4. I, III, IV
Subtopic:   Evolution of Periodic Table |
 65%
Level 2: 60%+
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There are four elements 'p', 'q', 'r' and 's' having atomic number Z-1, Z, Z+1 and Z+2 respectively. If there element 'q' is an inert gas, select the correct answers from the following statements.

(i) 'p' has most negative electron gain enthalpy in the respective period.

(ii) 'r' is an alkali metal.

(iii) 's' exists in +2 oxidation state.

(1) (i) and (ii)                     

(2) (ii) and (iii)

(3) (i) and (iii)                     

(4) (i), (ii) and (iii)

Subtopic:   Evolution of Periodic Table |
 77%
Level 2: 60%+
Hints

Find the correct order of atomic/ionic sizes among the following:

(a) Al³⁺ < Mg²⁺ < Na⁺ < F⁻

(b) Al³⁺ < Mg²⁺ < Li⁺ < K⁺

(c) Fe⁴⁺ < Fe³⁺ < Fe²⁺ < Fe

(d) Mg > Al > Si > P

1. (a), (b) & (c)                       

2. (b), (c) & (d)

3. (a), (c)                          

4. (a), (b), (c) & (d)

Subtopic:  Atomic Size |
 66%
Level 2: 60%+
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Which of the following orders are correct for the ionization energies?

(A) \(  B a   <   S r   <   C a        \)                  
(B) \(S^{2 -} < S   < S^{2 +}\)
(C) \(C   <   O < N\)
(D) \(M g   <   A l   <   S i\)

1. A, B and D                             
2. A, C and D
3. A, B and C                             
4. A, B, C and D

Subtopic:  Ionization Energy (IE) |
 56%
Level 3: 35%-60%
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