Consider the following ionisation reactions :

I.E. (kJ $mo{l}^{-1}$)

$A_{\left(g\right)}\to A_{\left(g\right)}^{+}+e^{-}<mspace\; width="1em"></mspace>,<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>A_1$
$B_{\left(g\right)}^{+}\to B_{\left(g\right)}^{2+}+e^{-},<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>B_2$
$C_{\left(g\right)}^{+}\to C_{\left(g\right)}^{2+}+e^{-},<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>C_2$
$B_{\left(g\right)}\to B_{\left(g\right)}^{+}+e^{-},<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>B_1$
$C_{\left(g\right)}\to C_{\left(g\right)}^{+}+e^{-},<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>C_1$
$C_{\left(g\right)}^{2+}\to C_{\left(g\right)}^{3+}+e^{-},<mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace><mspace\; width="1em"></mspace>C_3$

If monovalent positive ion of A, divalent positive ion of B and trivalent positive ion of C have zero electron. Then incorrect order of corresponding I.E. is :

(1) $C_3>C_2>B_2$                       

(2) $B_1>A_1>C_1$

(3) $C_3>C_2>B_2$                       

(4) $B_2>C_3>A_1$

The incorrect match among the following options is:

 Which of the following orders is correct for the property mentioned in brackets?
 1.S²⁻ > Cl⁻ > K⁺ > Ca²⁺ (Ionisation energy)
 2. C < N < F < O (Second ionisation energy)
 3. B > Al > Ga > In > Tl (Electronegativity)
 4. Na⁺ > Li⁺ > Mg²⁺ > Be²⁺ > Al³⁺ (Ionic radius)

${\mathrm{IP}}_1$ and ${\mathrm{IP}}_2$ for Mg are 178 Kcal mol^–1 and 348 Kcal ${\mathrm{mol}}^{-1}$, respectively. The energy required for the reaction, $\mathrm{Mg}\to {\mathrm{Mg}}^{2+}$ $+$ $2{\mathrm{e}}^{-}$ will be:

1. +170 Kcal ${\mathrm{mol}}^{-1}$

2. +526 Kcal ${\mathrm{mol}}^{-1}$

3. –170 Kcal ${\mathrm{mol}}^{-1}$

4. –526 Kcal ${\mathrm{mol}}^{-1}$

Incorrect statement about characteristics regarding halogens is :

1. Ionization energy decreases with increase in atomic number.

2. Electronegativity decreases with increase in atomic number.

3. Electron affinity decreases with increase in atomic number.

4. Enthalpy of fusion increases with increase in atomic number. 

The process requiring the absorption of energy is :

1. $F\to F^{-}$

2. $H\to H^{-}$

3. $Cl\to C{l}^{-}$

4. $O\to O^{2-}$

Consider the following statements:

Choose the correct option from the given codes.

There are four elements 'p', 'q', 'r' and 's' having atomic number Z-1, Z, Z+1 and Z+2 respectively. If there element 'q' is an inert gas, select the correct answers from the following statements.

(i) 'p' has most negative electron gain enthalpy in the respective period.

(ii) 'r' is an alkali metal.

(iii) 's' exists in +2 oxidation state.

(1) (i) and (ii)                     

(2) (ii) and (iii)

(3) (i) and (iii)                     

(4) (i), (ii) and (iii)

Given below are four orders for the size of the species. Choose the correct ones:

(a) ${\mathrm{Al}}^{3+}<{\mathrm{Mg}}^{2+}<{\mathrm{Na}}^{+}<{\mathrm{F}}^{-}$

(b) ${\mathrm{Al}}^{3+}<{\mathrm{Mg}}^{2+}<$ ${\mathrm{Li}}^{+}<{\mathrm{K}}^{+}$

(c) ${\mathrm{Fe}}^{4+}<{\mathrm{Fe}}^{3+}<{\mathrm{Fe}}^{2+}<\mathrm{Fe}$

(d) $\mathrm{Mg}>\mathrm{Al}>\mathrm{Si}>\mathrm{P}$

1. (a), (b) & (c)                       

2. (b), (c) & (d)

3. (a), (c)                          

4. (a), (b), (c) & (d)

Which of the following orders are correct for the ionization energies?

(A) \(  B a   <   S r   <   C a        \)                  
(B) \(S^{2 -} < S   < S^{2 +}\)
(C) \(C   <   O < N\)
(D) \(M g   <   A l   <   S i\)

1. A, B and D                             
2. A, C and D
3. A, B and C                             
4. A, B, C and D