1. Consider the given reaction:
\(A(g) \xrightarrow{k=0.1 M \min ^{-1}} 2 B(\mathrm{~g}) \)
If the initial concentration of A is 0.5 M, which of the following graphs correctly represents the concentration of B over time?
2. The activation energy of one of the reactions in a biochemical process is
\(\mathrm{532611~ J~ mol^{–1} .}\) When the temperature falls from
\(\mathrm{310~ K}\) to
\(\mathrm{300~ K,}\) the change observed in the rate constant is
\(\mathrm{k_{300} = x × 10^{–3} k_{310}.}\)
The value of
\(\mathrm{x}\) is:
[Given: ln
\(\mathrm{10 = 2.3, R = 8.3 ~JK^{–1} mol^{–1}}\)]
3. Consider the following first-order reactions:
\(A \rightarrow C ; t_{1/2}=15 \mathrm{~min}, B \rightarrow D ; t_{1/2}=5 \mathrm{~min} \)
The initial concentrations of A and B are 1 molar and 8 molar respectively. The time when the concentration of A and B becomes equal is ‘X’ minutes. The value of 2X is:
1. 40 min
2. 50 min
3. 45 min
4. 54 min
4. Select the correct option based on the statements below:
| Statement 1: |
The overall order of a reaction is the sum of the powers of all the reactants in the rate expression. |
| Statement 2: |
Examples of higher-order reactions (order > 2) are abundant.
|
| 1. |
Both Statement 1 and Statement 2 are true.
|
| 2. |
Both Statement 1 and Statement 2 are false
|
| 3. |
Statement 1 is true, but Statement 2 is false.
|
| 4. |
Statement 1 is false, but Statement 2 is true.
|
5. Which of the following statements is/are incorrect?
| (i) |
A catalyst lowers the activation energy of a reaction. |
| (ii) |
A catalyst allows the same rate of reaction to be achieved at a lower temperature. |
| (iii) |
A catalyst mixes with the reactants and increases the overall concentration of reactants in the rate equation. |
1.
i only
2.
i and
ii only
3.
ii and
iii only
4.
iii only
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