For the elementary reaction M N, the rate of disappearance of M increases by a factor of 8 upon doubling the concentration of M.
The order of the reaction with respect to M will be:
1. 4
2. 3
3. 2
4. 1
The rate constant of a first-order reaction is\(4 \times 10^{-3} \mathrm{sec}^{-1}.\) At a reactant concentration of \(0.02~\mathrm{M},\) the rate of reaction would be:
| 1. | \(8 \times 10^{-5} \mathrm{M} ~\mathrm{sec}^{-1} \) | 2. | \(4 \times 10^{-3} \mathrm{M} ~\mathrm{sec}^{-1} \) |
| 3. | \(2 \times 10^{-1} \mathrm{M}~ \mathrm{sec}^{-1} \) | 4. | \(4 \times 10^{-1} \mathrm{M}~ \mathrm{sec}^{-1}\) |
For a first-order reaction A Products, the rate of reaction at [A] = 0.2 M is 1.0 x 10-2 mol litre-1 min-1. The half-life period for the reaction will be:
| 1. | 832 sec | 2. | 440 sec |
| 3. | 416 sec | 4. | 14 sec |
In the following reaction: xA → yB
where the -ve sign indicates the rate of disappearance of the reactant. Then, x : y equals:
| 1. | 1:2 | 2. | 2:1 |
| 3. | 3:1 | 4. | 3:10 |
Half-life is independent of the concentration of a reactant. After 10 minutes, the volume of N2 gas is 10 L and after complete reaction, it is 50 L. Hence, the rate constant is:
1. log 5 min-1
2. log 1.25 min-1
3. log 2 min-1
4. log 4 min-1
A gaseous reaction A2(g) → B(g) + (g) shows increase in pressure from 100 mm to 120 mm in 5 minutes. The rate of disappearance of A2 will be :
| 1. | 4 mm min-1 | 2. | 8 mm min-1 |
| 3. | 16 mm min-1 | 4. | 2 mm min-1 |
During the formation of ammonia by Haber's process N2 + 3H2 → 2NH3, the rate of appearance of NH3 was measured as 2.5 x 10-4 mol L-1 s-1. The rate of disappearance of H2 will be:
1. 2.5 x 10-4 mol L-1 s-1
2. 1.25 x 10-4 mol L-1 s-1
3. 3.75 x 10-4 mol L-1 s-1
4. 15.00 x 10-4 mol L-1 s-1
During the kinetic study of the reaction, 2A + B → C + D, the following results were obtained:
| Run | [A]/mol L-1 | [B]/mol L-1 | Initial rate of formation of D/mol L-1 min-1 |
| I | 0.1 | 0.1 | 6.0x10-3 |
| II | 0.3 | 0.2 | 7.2x10-2 |
| III | 0.3 | 0.4 | 2.88x10-1 |
| IV | 0.4 | 0.1 | 2.40x10-2 |
Based on the above data, the correct rate law is:
1. Rate=k[A]2[B]
2. Rate=k[A][B]
3. Rate=k[A]2[B]2
4. Rate=k[A][B]2
A first-order reaction is 15 % completed in 20 minutes. The amount of time required to complete 60 % of the reaction is:
| 1. | 112.8 min | 2. | 120.7 min |
| 3. | 100.4 min | 4. | 140.7 min |
If ‘a’ is the initial concentration of a substance which reacts according to zero-order kinetics and k is the rate constant, the time for the reaction to go to completion will be:
| 1. | a/k | 2. | 2/ka |
| 3. | k/a | 4. | Infinite |
For a given reaction the concentration of the reactant plotted against time gave a straight line with negative slope.
The order of the reaction will be:
1. 3
2. 2
3. 1
4. 0
If in the fermentation of sugar in an enzymatic solution that is 0.12 M, the concentration of the sugar is reduced to 0.06 M in
10 h and to 0.03 M in 20 h, the order of the reaction will be:
1. 1
2. 2
3. 3
4. 0
Which of the following statements about the order of reaction is incorrect?
| 1. | Order is not influenced by the stoichiometric coefficient of the reactants. |
| 2. | Order of reaction is the sum of power to the concentration terms of reactants to express the rate of reaction. |
| 3. | The order of reaction is always a whole number. |
| 4. | Order can be determined by experiments only. |
If 60 % of a first-order reaction is completed in 60 minutes, 50 % of the same reaction takes approximately:
(log4 = 0.60, log5 = 0.69)
| 1. | 55 min | 2. | 45 min |
| 3. | 60 min | 4. | 30 min |
Select the correct option based on statements below:
| Assertion (A): | The overall order of reaction is the sum of the power of all the reactants in the rate expression. |
| Reason (R): | There are many higher-order reactions. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
1. Pseudo-first-order reaction
2. First-order reaction
3. Second order reaction
4. Third-order reaction
For a general reaction A B, the plot of the concentration of A vs. time is given in the figure.
The slope of the curve will be:
| 1. | -k | 2. | -k/2 |
| 3. | -k2 | 4. | -k/3 |
Consider the first-order gas-phase decomposition reaction given below.
A(g) → B(g) + C(g)
The initial pressure of the system before the decomposition of A was . After the lapse of time t, the total pressure of the system increased by X units and became . The rate constant k for the reaction is:
| 1. | 2. | ||
| 3. | 4. |
A first-order reaction is 50 % completed in 1.26 × 1014 s.
The time required for 100 % completion of the reaction will be:
1. 1.26 × 1015 s
2. 2.52 × 1014 s
3. 2.52 × 1028 s
4. Infinite
Match the graph given in Column I with the order of reaction given in Column II.
More than one item in Column I may be linked to the same item in Column II:
| Column I | Column II | ||
| (i) | (a) | 1st order | |
| (ii) | (b) | Zero order | |
| (iii) | |||
| (iv) | |||
| (i) | (ii) | (iii) | (iv) | |
| 1. | (a) | (b) | (a) | (b) |
| 2. | (a) | (b) | (b) | (a) |
| 3. | (a) | (a) | (b) | (b) |
| 4. | (b) | (b) | (a) | (a) |