The source of nitrogen in Gabriel synthesis of amines is:

1. Sodium amide, NaN3

2. Sodium azide, NaNO2

3. Potassium cyanide, KCN

4. Potassium phthalimide C6H4(CO)2NK+

Subtopic:  Amines - Preparation & Properties |
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Level 1: 80%+
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Amongst the given set of reactants, the most appropriate for preparing 2o amine is: 

1. 2o  R - Br + NH3
2. 2oR — Br + NaCN followed by H2/Pt
3. 1o R —NH2 + RCHO followed by H2/Pt
4. 1o R — Br(2 mol) + potassium phthalimide followed by H3O+/ heat
Subtopic:  Amines - Preparation & Properties |
Level 3: 35%-60%
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The most effective reagent among the following to convert 2-phenylpropanamide into 2-phenylpropanamine is:
1. Excess H2
2. Br2 in aqueous NaOH
3. Iodine in the presence of phosphorus
4. LiAlH4 in ether

Subtopic:  Amines - Preparation & Properties |
 60%
Level 2: 60%+
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The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is .... ....

1.  Excess H2 / Pt

2.  NaOH / Br2

3. NaBH4 / Methanol

4.  LiAlH4 / Ether

Subtopic:  Amines - Preparation & Properties |
 79%
Level 2: 60%+
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Hofmann bromamide degradation reaction is shown by:

1 PhNH2 2. PhCONH2
3. PhNO2 4. PhCH2NH2
Subtopic:  Amines - Preparation & Properties |
 89%
Level 1: 80%+
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The correct increasing order of basic strength for the following compounds is:

(I) (II) (III)

 
1. II < III < I

2. III < I < II

3. III < II < I

4. II < I < III

Subtopic:  Amines - Preparation & Properties |
 87%
Level 1: 80%+
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What is the product formed when methylamine reacts with nitrous acid?

1. CH3-O-N=O 2. CH3-O-CH3
3. CH3-OH 4. CH3CHO
Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 74%
Level 2: 60%+
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The gas evolved when methylamine reacts with nitrous acid is:

1. NH3
2. N2
3. H2
4. C2H6

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 85%
Level 1: 80%+
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In nitration of benzene using a mixture of conc. H2SO4 and conc. HNO3, the species that initiates the reaction is :

1. NO2
2. NO+
3. NO2+
4. NO2-

Subtopic:  Urea & Nitro Compound |
 79%
Level 2: 60%+
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Reduction of aromatic nitro compounds using Fe and HCl gives:

1.  Aromatic oxime

2.  Aromatic hydrocarbon

3.  Aniline

4.  Aromatic amide

Subtopic:  Amines - Preparation & Properties |
 90%
Level 1: 80%+
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