Assertion (A): | Aldehydes and ketones give nucleophilic addition reaction but acyl derivatives give nucleophilic substitution reaction. |
Reason (R): | Aldehydes and ketones contain stronger bases and poor leaving groups in comparison to acyl derivatives. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
The values of some of the acids are given below:
Acid | \(\mathrm{pK_a}\) | Acid | \(\mathrm{pK_a}\) |
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-0.6 | HI | -10.0 |
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4.8 | \(\mathrm{HC} \equiv \mathrm{CH}\) | 25 |
\(\overset{+}{N}H_4\) | 9.4 | \(H_2S\) | 7.0 |
The correct order of leaving tendency of their conjugate bases is:
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