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| 1. | \(\small {\mathrm{HCOOH}>\mathrm{CH}_3 \mathrm{COOH}> \left(\mathrm{CH}_3\right)_2 \mathrm{CHCOOH} }\) \(\small {> \left(\mathrm{CH}_3\right)_3 \mathrm{CCOOH}} \) |
| 2. | \(\small {\mathrm{HCOOH}>\left(\mathrm{CH}_3\right)_3 \mathrm{CCOOH}> \left(\mathrm{CH}_3\right)_2 \mathrm{CHCOOH}}\) \( \small{ > \mathrm{CH}_3 \mathrm{COOH}} \) |
| 3. | \(\small { \left(\mathrm{CH}_3\right)_3 \mathrm{CCOOH}>\left(\mathrm{CH}_3\right)_2 \mathrm{CHCOOH}> \mathrm{CH}_3 \mathrm{COOH}}\) \(\small {>\mathrm{HCOOH}} \) |
| 4. | \(\small {\mathrm{CH}_3 \mathrm{COOH}>\left(\mathrm{CH}_3\right)_2 \mathrm{CHCOOH}> \left(\mathrm{CH}_3\right)_3\mathrm{CCOOH} }\) \(\small {>\mathrm{HCOOH}} \) |
| 1. | (i) \(NaBH_4\), (ii) \(H^+/H_2O\) | 2. | \(H_2/ Pd-BaSO_4\) |
| 3. | (i) \(LiAlH_4\), (ii) \(H^+/H_2O\) | 4. | (i)\(AlH(iBu)_2\)(ii) \(H_2O\) |
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| 1. | Compound P is obtained by the hydrogenation of benzoyl chloride with Pd on \(BaSO_4\). |
| 2. | On treating compound P with saturated \(NaHCO_3\) solution, brisk effervescence is observed. |
| 3. | Compound P can be prepared by treating benzene with anhydrous \(AlCl_3\) and \(CH_3COC1\). |
| 4. | On treatment with bromine water, compound P gives a white precipitate. |
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| 1. | Both P and Q are carbonyl compounds. |
| 2. | If P is the sodium salt of a carboxylic acid, Q is a primary alcohol. |
| 3. | P and Q are aromatic compounds. |
| 4. | If P gives a carboxylic acid on acidification, Q gives a poisonous gas on exposure to air and light. |
| 1. | \(\mathrm{CH}_3 \mathrm{COCl} \xrightarrow[\Delta]{\mathrm{H}_2 \mathrm{O}} \mathrm{CH}_3 \mathrm{COOH}\) |
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| 3. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{\oplus}]{\text { (i) } \mathrm{KMnO}_{4}/\mathrm{OH^{-} }} \mathrm{CH}_3 \mathrm{COOH}\) |
| 4. | \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH} \xrightarrow{\mathrm{CrO}_3-\mathrm{H}_2 \mathrm{SO}_4} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH}\) |
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| List-I (Reagent) |
List-II (Name of the reaction) |
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| A | \(\mathrm{{H}_2, {Pd}-{Ba}S {O}_4}\) | I | Gattermann-Koch reaction |
| B | \(\mathrm{{(i) \; {CrO}_2 {Cl}_2, {CS}_2\\ (ii) ~{H}_2 {O}/H^+}}\) | II | Reimer-Tiemann reaction |
| C | \(\mathrm{{CO, HCl, Anhyd.~\\ {AlCl}_3 / {CuCl}}}\) | III | Etard reaction |
| D | \(\mathrm{{CHCl}_3, {NaOH}}\) | IV | Rosenmund reduction |