Q. No.Match the starting material in Column I with the products formed (Column II) in the reaction with HI.
Column I
Column II
A.
1.
B.
2.
C.
3.
D.
4.
5.
A
B
C
D
1.
2
3
4
1
2.
3
1
5
2
3.
5
4
3
2
4.
4
5
2
1
Column II
Match the items of Column I with items of Column II.
| Column l | Column ll |
| A. Solvent used in perfumes | I. Neutral ferric chloride |
| B. Wood spirit | II. Glycerol |
| C. Reagent used for detection of phenolic group | III. Methanol |
| D. By product of soap industry used in cosmetics | IV. Ethanol |
Codes:
| A | B | C | D | |
| 1. | II | III | IV | I |
| 2. | III | I | IV | II |
| 3. | I | IV | III | II |
| 4. | IV | III | I | II |
Match the reactions from Column-I with their corresponding descriptions from Column-II and select the correct option.
|
Column-l (Name of Reaction) |
Column-ll (Description of Reaction) |
||
| A. |
Reimer-Tiemann reaction |
I. |
Conversion of phenol to o-hydroxysalicylic aid |
| B. |
Kolbe's reaction |
II. |
Heated copper at 573K |
| C. |
Conversion of 2alcohol to a ketone |
III. |
Reaction of an alkyl halide |
| D. |
Williamson's synthesis |
Iv. |
Conversion of phenol to salicylaldehyde |
Codes:
| A | B | C | D | |
| 1. | II | III | IV | I |
| 2. | III | IV | I | II |
| 3. | I | IV | III | II |
| 4. | IV | I | II | III |
Select the correct option based on statements below:
| Assertion (A): | The addition reaction of water to but-1-ene in acidic medium yields butan-1-ol. |
| Reason (R): | Addition of water in an acidic medium proceeds through the formation of a primary carbocation. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
Select the correct option based on statements below:
| Assertion (A): | p-Nitrophenol is more acidic than phenol. |
| Reason (R): | Nitro group helps in the stabilization of the phenoxide ion by dispersal of negative charge due to resonance. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
| Assertion (A): | The IUPAC name of the compound is 2-ethoxy-2-methylethane. |
| Reason (R): | In IUPAC nomenclature, ether is regarded as a hydrocarbon derivative in which a hydrogen atom is replaced by —OR or -OAr group [where, R = alkyl group and Ar = aryl group]. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Select the correct option based on the statements below:
| Assertion (A): | The bond angle in ethers is slightly less than the angle of tetrahedral. |
| Reason (R): | There is repulsion between the two bulky (— R) groups. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
| Assertion (A): | Boiling points of alcohols and ethers are high. |
| Reason (R): | They can form intermolecular hydrogen bonding. |
| 1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
| 3. | (A) is true but (R) is false. |
| 4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
| Assertion (A): | o-Nitrophenol is less soluble in water than the m and p-isomers. |
| Reason (R): | m and p-Nitrophenols exist as associated molecules. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
| Assertion (A): | Ethanol is a weaker acid than phenol. |
| Reason (R): | Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
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