The correct order for boiling points of the following compounds is:
1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 |
2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 |
3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 |
4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |
1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?
1. | NH3 < PH3 < AsH3 < SbH3 | Increasing acidic character |
2. | CO2 < SiO2 < SnO2 < PbO2 | Increasing oxidizing power |
3. | HF < HCl < HBr < HI | Increasing acidic strength |
4. | H2O < H2S < H2Se < H2Te | Increasing pKa values |
Match the name of process given in column I with the name of compound given in
column II and mark the correct option.
(a) Pure nitrogen | (i) Chlorine |
(b) Haber process | (ii) Sulphuric acid |
(c) Contact process | (iii) Ammonia |
(d) Deacon's process | (iv) Sodium azide or Barium azide |
(a) | (b) | (c) | (d) | |
1. | (iv) | (iii) | (ii) | (i) |
2. | (i) | (ii) | (iii) | (iv) |
3. | (ii) | (iv) | (i) | (iii) |
4. | (iii) | (iv) | (ii) | (i) |
False statement regarding PCl5 is:
1. | PCl5 molecule is non-reactive. |
2. | Three equatorial P-Cl bonds make an angle of 120° with each other. |
3. | Two axial P-Cl bonds make an angle of 180° with each other. |
4. | Axial P-Cl bonds are longer than equatorial P-Cl bonds. |
A compound "X", upon reaction with H2O, produces a colourless gas "Y" with a rotten fish smell. Gas 'Y' is absorbed in a solution of CuSO4 to give Cu3P2 as one of the products. The compound 'X' will be:
1. Ca3P2
2.
3.
4. Ca3(PO4)2
Among the following oxoacids of phosphorus ,the strongest reducing property is for:
1. H4P2O7
2. H3PO3
3. H3PO2
4. H3PO4
Which of the following is the incorrect statement?
1. PH5 and BiCl5 do not exist
2. pπ - dπ bonds are present in SO2
3. SeF4 and CH4 have the same shape
4. \(I_{3}^{+}\)
1. | Phosphinic acid is a monoprotic acid while phosphonic acid is a diprotic acid |
2. | Phosphinic acid is a diprotic acid while phosphonic acid is a monoprotic acid |
3. | Both are triprotic acids |
4. | Both are diprotic acids |
The strong reducing behaviour of H3PO2 is due to:
1. Presence of one -OH group and two P-H bonds.
2. High electron gain enthalpy of phosphorus.
3. High oxidation state of phosphorus.
4. Presence of two -OH groups and one P-H bond.