The correct order for boiling points of the following compounds is: 

1. AsH3 > PH3 > NH3 > SbH3 > BiH3
2. BiH3 > SbH3 > NH3 > AsH3 > PH3
3. NH3 > PH3 > AsH3 > SbH3 > BiH3
4. PH3 > NH3 > AsH3 > SbH3 > BiH3
Subtopic:  Group 15 - Preparation, Properties & Uses |
 63%
From NCERT
NEET - 2022
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The reaction that is a part of large scale industrial preparation of nitric acid is: 
1. \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\)
2. \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\)
3. \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\)
4. \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\)
Subtopic:  Group 15 - Preparation, Properties & Uses |
 62%
From NCERT
NEET - 2022
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In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?

1. NH< PH< AsH< SbH3 Increasing acidic character
2. CO< SiO< SnO< PbO2 Increasing oxidizing power
3. HF < HCl < HBr < HI Increasing acidic strength
4. H2O < H2S < H2Se < H2Te Increasing pKa values
Subtopic:  Group 15 - Preparation, Properties & Uses |
 64%
From NCERT
NEET - 2021
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Match the name of process given in column I with the name of compound given in
column II and mark the correct option.

(a) Pure nitrogen (i) Chlorine
(b) Haber process (ii) Sulphuric acid
(c) Contact process (iii) Ammonia
(d) Deacon's process (iv) Sodium azide or Barium azide
 
(a) (b) (c) (d)
1. (iv) (iii) (ii) (i)
2. (i) (ii) (iii) (iv)
3. (ii) (iv) (i) (iii)
4. (iii) (iv) (ii) (i)
Subtopic:  Group 15 - Preparation, Properties & Uses |
 88%
From NCERT
NEET - 2019
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False statement regarding PCl5 is:

1. PCl5 molecule is non-reactive.
2. Three equatorial P-Cl bonds make an angle of 120° with each other.
3. Two axial  P-Cl bonds make an angle of 180° with each other.
4. Axial P-Cl bonds are longer than equatorial P-Cl bonds.

Subtopic:  Group 15 - Preparation, Properties & Uses |
 76%
From NCERT
NEET - 2019
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A compound "X", upon reaction with H2O, produces a colourless gas "Y" with a rotten fish smell.  Gas 'Y' is absorbed in a solution of CuSO4 to give Cu3P2 as one of the products. The compound 'X' will be:

1. Ca3P2

2. NH4Cl

3. As2O3

4. Ca3(PO4)2

Subtopic:  Group 15 - Preparation, Properties & Uses |
 71%
From NCERT
NEET - 2019
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Among  the following oxoacids of phosphorus ,the strongest reducing property is for:

1. H4P2O7

2. H3PO3

3. H3PO2

4. H3PO4

Subtopic:  Group 15 - Preparation, Properties & Uses |
 66%
From NCERT
NEET - 2019
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Which of the following is the incorrect statement?

1. PH5  and BiCl5  do not exist

2. pπ - dπ bonds are present in SO2

3. SeF4 and CH4  have the same shape

4. \(I_{3}^{+}\) has bent geometry

Subtopic:  Group 17 - Preparation, Properties & Uses | Group 16 - Preparation, Properties & Uses | Group 15 - Preparation, Properties & Uses |
 68%
From NCERT
NEET - 2016
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Which is the correct statement for the given acids?
 
1. Phosphinic acid is a monoprotic acid while phosphonic acid is a diprotic acid
2. Phosphinic acid is a diprotic acid while phosphonic acid is a monoprotic acid
3. Both are triprotic acids
4. Both are diprotic acids
Subtopic:  Group 15 - Preparation, Properties & Uses |
 71%
From NCERT
NEET - 2016
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The strong reducing behaviour of H3PO2 is due to:

1. Presence of one -OH group and two P-H bonds.

2. High electron gain enthalpy of phosphorus.

3. High oxidation state of phosphorus.

4. Presence of two -OH groups and one P-H bond.

Subtopic:  Group 15 - Preparation, Properties & Uses |
 78%
From NCERT
NEET - 2015
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