\(Cu(s)|Cu^{+2}(10^{-3} \ M) \ || \ Ag^{+}(10^{-5} \ M)|Ag(s)\)
if \(E_{Cu^{+2}/Cu}^{o} \ = \ +0.34 \ V\), and \(E_{Ag^{+}/Ag}^{o} \ = \ +0.80 \ V\)
Ecell will be: 

1. 0.46 V
2. \(0.46-\frac{RT}{2F}ln10^{7}\)
3. \(0.46+\frac{RT}{2F}ln10^{7}\)
4. \(0.46-\frac{RT}{2F}ln10^{2}\)

Subtopic:  Nernst Equation |
 55%
Level 3: 35%-60%
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Consider the following cell reaction 

2Fe(s) + O2(g) + 4H+(aq)  2Fe2+(aq) + 2H2O(l)

E° = 1.67 V, At [Fe2+] = 10-3 M, PO2 = 0.1 atm and pH = 3, the cell potential at 25 °C is : 

1. 1.27 V

2. 1.77 V

3. 1.87 V

4. 1.57 V

Subtopic:  Nernst Equation |
 57%
Level 3: 35%-60%
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The electrode potential for Mg electrode varies according to the equation

\(E_{Mg^{2+}/Mg}\ = \ E_{Mg^{2+}/Mg}^{o} \ - \ \frac{0.059}{2}log\frac{1}{[Mg^{2+}]}\) 

The graph of EMg2+ / Mg vs log [Mg2+] among the following is:

1.    2.  
3.    4.  
Subtopic:  Nernst Equation |
 62%
Level 2: 60%+
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The correct statement among the following options is: 

1. Ecell and ∆rG of cell reaction are both extensive properties.
2. Ecell and ∆rG of cell reaction are both intensive properties.
3. Ecell is an intensive property while ∆rG of cell reaction is an extensive property.
4. Ecell is an extensive property while ∆rG of cell reaction is an intensive property.

Subtopic:  Electrode & Electrode Potential |
 75%
Level 2: 60%+
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The incorrect statement about the solution of electrolytes is:

1. Conductivity of solution depends upon the size of ions.
2. Conductivity depends upon the viscosity of solution.
3. Conductivity does not depend upon the solvation of ions present in solution.
4. Conductivity of solution increases with temperature.
Subtopic:  Conductance & Conductivity |
 75%
Level 2: 60%+
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The most stable oxidized species among the following is: 
\(E_{{\mathrm{Cr}_2 \mathrm{O}_7^2}/ \mathrm{Cr}^{3+}}^{o} =1.33 \mathrm{~V} ; E_{\mathrm{Cl}_2 / \mathrm{Cl}^{-}}^{o}=1.36 \mathrm{~V} \)
\( E_{\mathrm{MnO_{4}}^{-} / \mathrm{Mn}^{2+}}^{o}=1.51 \mathrm{~V} ; E_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^{o}=-0.74 \mathrm{~V}\)

1. Cr3+  2. MnO4-
3. Cr2O72- 4. Mn2+ 
Subtopic:  Electrochemical Series |
 61%
Level 2: 60%+
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Match Column-I (Types of cell) with Column-II (Characteristics shown by cells) and mark the appropriate option:

Column I
(Type of cell)
Column II
(Characteristics)
A Lechlanche cell  1. Cell reaction 2H2 +O2 → 2H2O
B Ni-Cd cell  2. Does not involve any ion in solution and is used in hearing aids.
C Fuel cell  3.  Rechargeable
Mercury cell  4. -Reaction at anode, Zn  → Zn2+ + 2e-

Codes:

Options:  A   B   C   D 
1. 2  3  4  1
2.  4 3 1 2
3. 1 4 3 2
4. 4 1 3 2

Subtopic:  Batteries & Salt Bridge |
 84%
Level 1: 80%+
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Given below are two statements: 

Assertion (A): Cu is less reactive than hydrogen.
Reason (R):  Cu2+/ Cu is negative.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.

Subtopic:  Electrochemical Series |
 68%
Level 2: 60%+
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In a typical fuel cell, the reactants (R) and products (P) are: 

1. R = H2(g), O2(g); P = H2O2(l)
2. R = H2(g), O2(g); P = H2O(l)
3. R = H2(g), O2(g), C l2(g); P = HClO4(aq)
4. R = H2(g), N2(g); P = NH3(aq)

Subtopic:  Batteries & Salt Bridge |
 75%
Level 2: 60%+
NEET - 2020
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The value of E0 cell for the following reaction is:
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ } \)

(Given, equilibrium constant is 106)

1. 0.17 2. 0.01
3. 0.05 4. 1.77
Subtopic:  Electrode & Electrode Potential |
 75%
Level 2: 60%+
AIPMT - 1999
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